柴油安全技术说明书 (1)

柴油安全技术说明书 (1) 柴油安全技术说明书 第一部分 化学品名称 化学品中文名称:柴油 化学品英文名称:diesel oil 第二部分 成分/组成信息 混合物?:由各族烃类和非烃类的组成的 化学品名称:柴油 有害物成分:烷烃、环烷烃和芳香烃、含硫、氧、氮化合物 第三部分 危险性概述 危险性类别: 可燃液体 侵入途径:吸入、食入、经皮吸收 健康危害:急性中毒:吸入高浓度煤油蒸气～常先有兴奋～后转入抑制～表现为乏力、头痛、酩酊感、神志恍惚、肌肉震颤、共济运动失调,严重者出现定向力障碍、谵妄、意识模糊等,蒸气可引起眼及呼吸道刺激症状～重者出现化学性肺炎。吸入液态煤油可引起吸入性肺炎～严重时可发生肺水肿。摄入引起口腔、咽喉和胃肠道刺激症状～可出现与吸入中毒相同的中枢神经系统症状。 慢性影响:神经衰弱综合征为主要表现～还有眼及呼吸道刺激症状～接触性皮炎～皮肤干燥等。 环境危害:对环境有危害。对大气可造成污染。 燃爆危险:其蒸气与空气可形成爆炸性混合物～遇明火、高热能引起燃烧爆炸。其蒸气比空气重～能在较低处扩散到相当远的地方～遇火源会着火回燃。若遇高 provides venture platform, makes many youth round has venture dream, for national solution has important of employment problem. Relevant departments units carefully to discover, cultivate talent. From the perspective of Dongping, contradiction of rapid economic development and personnel shortages. Currently facing the industry transformation and upgrading, and transform and upgrade traditional industries, is the development of new industries such as tourism, logistics, e-commerce, we still lack a large number of capital operation and management of talents, the lack of technological innovation, technology transfer, product research and development, tourism services and other high-level professional and technical personnel. Especially with theIndustry further develops, the demand is growing. We must stand in the global and strategic height, with a high degree of political responsibility and historical mission, counties implement talent strategies as a major and pressing task to seize good, practical human resource development as industrial counties of the country. Departments at all levels must firmly establish the "talent is wealth, talent is competitive, talent is creativity" concept, fully aware of the extreme importance of talent, the real talent working on the agenda, the primary task of the primary resources to support the development of talent. 2 the construction of enterprisers ' as the starting point, and promote the transformation and 热～容器内压增大～有开裂和爆炸的危险。 第四部分 急救措施 皮肤接触:立即脱去所有被污染的衣物～包括鞋类。用流动清水冲洗皮肤和头发,可用肥皂,。如果出现刺激症状～就医。 眼睛接触:立即用流动、清洁水冲洗至少15分钟。如果疼痛持续或复发～就医。眼睛受伤后～应由专业人员取出隐形眼镜。 吸入:如果吸入本品气体或其燃烧产物～脱离污染区。把病人放卧位～保暖并使其安静。开始急救前～首先取出假牙等～防止阻塞气道。如果呼吸停止～立即进行人工呼吸～用活瓣气囊面罩通气或有效的袖珍面具可能效果更佳。呼吸心跳停止～立即进行心肺复苏术。送医院或寻求医生帮助。 食入:禁止催吐。如果发生呕吐～让病人前倾或左侧位躺下,头部保持低位,～保持呼吸道通畅～防止吸入呕吐物。仔细观察病情。禁止给有嗜睡症状或知觉降低～即正在失去知觉的病人服用液体。意识清醒者可用水漱口～然后尽量多饮水。寻求医生或医疗机构的帮助。 第五部分 消防措施 危险特性:其蒸气与空气可形成爆炸性混合物～遇明火、高热能引起燃烧爆炸。与氧化剂可发生反应。流速过快～容易产生和积聚静电。其蒸气比空气重～能在较低处扩散到相当远的地方～遇火源会着火回燃。若遇高热～容器内压增大～有开裂和爆炸的危险。 有害燃烧产物:一氧化碳、二氧化碳。 灭火方法:尽可能将容器从火场移至空旷处。喷水保持火场容器冷却～直至灭火结束。处在火场中的容器若已变色或从安全泄压装置中产生声音～必须马上撤离。 provides venture platform, makes many youth round has venture dream, for national solution has important of employment problem. Relevant departments units carefully to discover, cultivate talent. From the perspective of Dongping, contradiction of rapid economic development and personnel shortages. Currently facing the industry transformation and upgrading, and transform and upgrade traditional industries, is the development of new industries such as tourism, logistics, e-commerce, we still lack a large number of capital operation and management of talents, the lack of technological innovation, technology transfer, product research and development, tourism services and other high-level professional and technical personnel. Especially with theIndustry further develops, the demand is growing. We must stand in the global and strategic height, with a high degree of political responsibility and historical mission, counties implement talent strategies as a major and pressing task to seize good, practical human resource development as industrial counties of the country. Departments at all levels must firmly establish the "talent is wealth, talent is competitive, talent is creativity" concept, fully aware of the extreme importance of talent, the real talent working on the agenda, the primary task of the primary resources to support the development of talent. 2 the construction of enterprisers ' as the starting point, and promote the transformation and 用雾状水、泡沫、干粉、二氧化碳、砂土灭火。 灭火注意事项:消防人员须佩戴防毒面具、穿全身消防服～在上风向灭火。 第六部分 泄漏应急处理 应急行动:迅速撤离泄漏污染区人员至安全区～并进行隔离～严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器～穿防静电工作服。尽可能切断泄漏源。防止流入下水道、排洪沟等限制性空间。小量泄漏:用砂石或其它不燃材料吸附或吸收。也可以在保证安全情况下～就地焚烧。大量泄漏:构筑围堤或挖坑收容。用泵转移至槽车或专用收集器内～回收或运至废物处理场所处置。 第七部分 操作处置与储存 操作处置注意事项:密闭操作～全面通风。操作人员必须经过专门培训～严格遵守操作规程。建议操作人员佩戴自吸过滤式防毒面具,半面罩,～戴化学安全防护眼镜～穿防静电工作服～戴橡胶耐油手套。远离火种、热源～工作场所严禁吸烟。使用防爆型的通风系统和设备。防止蒸气泄漏到工作场所空气中。避免与氧化剂接触。灌装时应控制流速～且有接地装置～防止静电积聚。搬运时要轻装轻卸～防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。 储存注意事项:储存于阴凉、通风的库房。远离火种、热源。炎热季节库温不得超过25?。应与氧化剂、食用化学品分开存放～切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。 第八部分 接触控制/个体防护 provides venture platform, makes many youth round has venture dream, for national solution has important of employment problem. Relevant departments units carefully to discover, cultivate talent. From the perspective of Dongping, contradiction of rapid economic development and personnel shortages. Currently facing the industry transformation and upgrading, and transform and upgrade traditional industries, is the development of new industries such as tourism, logistics, e-commerce, we still lack a large number of capital operation and management of talents, the lack of technological innovation, technology transfer, product research and development, tourism services and other high-level professional and technical personnel. Especially with theIndustry further develops, the demand is growing. We must stand in the global and strategic height, with a high degree of political responsibility and historical mission, counties implement talent strategies as a major and pressing task to seize good, practical human resource development as industrial counties of the country. Departments at all levels must firmly establish the "talent is wealth, talent is competitive, talent is creativity" concept, fully aware of the extreme importance of talent, the real talent working on the agenda, the primary task of the primary resources to support the development of talent. 2 the construction of enterprisers ' as the starting point, and promote the transformation and 职业接触限值: MAC,mg/m3,:未制定 标准 excel标准偏差excel标准偏差函数exl标准差函数国标检验抽样标准表免费下载红头文件格式标准下载 PC—TWA,mg/m3,:未制定标准 PC—STEL,mg/m3,:未制定标准 工程控制:生产过程密闭～全面通风。提供安全淋浴和洗眼设备 呼吸系统防护:空气中浓度超标时～建议佩戴自吸过滤式防毒面具,半面罩,。紧急事态抢救或撤离时～应该佩戴空气呼吸器。 眼睛防护:戴化学安全防护眼镜。 身体防护:穿防静电工作服。 手防护:戴橡胶耐油手套。 其他防护:工作现场严禁吸烟。避免长期反复接触 第九部分 理化特性 外观与性状: 有色透明液体～挥发 pH值: 中性 熔点,?,: 无资料 相对密度,水=1,:0.70—0.75 沸点,?,:180-360 相对蒸气密度,空气=1,: 1.59-4 饱和蒸气压,kPa,: 燃烧热,kJ/l,: 30000—46000 临界温度,?,: 临界压力,MPa,: 辛醇/水分配系数的对数值: 无资料 闪点,?,:45-90 爆炸上限,,V/V,: 6.5 引燃温度,?,:75-120 爆炸下限,,V/V,: 0.6 溶解性: 不溶于水～溶于醇等溶剂 provides venture platform, makes many youth round has venture dream, for national solution has important of employment problem. Relevant departments units carefully to discover, cultivate talent. From the perspective of Dongping, contradiction of rapid economic development and personnel shortages. Currently facing the industry transformation and upgrading, and transform and upgrade traditional industries, is the development of new industries such as tourism, logistics, e-commerce, we still lack a large number of capital operation and management of talents, the lack of technological innovation, technology transfer, product research and development, tourism services and other high-level professional and technical personnel. Especially with theIndustry further develops, the demand is growing. We must stand in the global and strategic height, with a high degree of political responsibility and historical mission, counties implement talent strategies as a major and pressing task to seize good, practical human resource development as industrial counties of the country. Departments at all levels must firmly establish the "talent is wealth, talent is competitive, talent is creativity" concept, fully aware of the extreme importance of talent, the real talent working on the agenda, the primary task of the primary resources to support the development of talent. 2 the construction of enterprisers ' as the starting point, and promote the transformation and 主要用途: 用于柴油机 其他理化性质: 第十部分 稳定性和反应活性 稳定性: 常温常压下稳定 禁配物: 强氧化剂 避免接触的条件:明火、高温 聚合危害: 不能发生 分解产物: 一氧化碳 二氧化碳 第十一部分 毒理学资料 急性毒性: Ld50:>5 000mg/kg,大鼠经口, LC50:>5 000mg/m3/4h(大鼠吸入) 刺激性:家兔经皮:500mg～严重刺激。 第十二部分 生态学资料 生态毒性:无资料。 生物降解性:无资料。 非生物降解性:无资料。 第十三部分 废弃处置 废弃物性质:危险废物 废弃处置方法:建议用焚烧法处置。 废弃注意事项:处置前应参阅国家和地方有关法规 第十四部分 运输信息 provides venture platform, makes many youth round has venture dream, for national solution has important of employment problem. Relevant departments units carefully to discover, cultivate talent. From the perspective of Dongping, contradiction of rapid economic development and personnel shortages. Currently facing the industry transformation and upgrading, and transform and upgrade traditional industries, is the development of new industries such as tourism, logistics, e-commerce, we still lack a large number of capital operation and management of talents, the lack of technological innovation, technology transfer, product research and development, tourism services and other high-level professional and technical personnel. Especially with theIndustry further develops, the demand is growing. We must stand in the global and strategic height, with a high degree of political responsibility and historical mission, counties implement talent strategies as a major and pressing task to seize good, practical human resource development as industrial counties of the country. Departments at all levels must firmly establish the "talent is wealth, talent is competitive, talent is creativity" concept, fully aware of the extreme importance of talent, the real talent working on the agenda, the primary task of the primary resources to support the development of talent. 2 the construction of enterprisers ' as the starting point, and promote the transformation and 运输注意事项:运输前应先检查包装容器是否完整、密封～运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。夏季最好早晚运输。运输时所用的槽,罐,车应有接地链～槽内可设孔隔板以减少震荡产生静电。严禁与氧化剂、卤素、食用化学品等混装混运。运输途中应防曝晒、雨淋～防高温。中途停留时应远离火种、热源、高温区。装运该物品的车辆排气管必须配备阻火装置～禁止使用易产生火花的机械设备和工具装卸。运输车船必须彻底清洗、消毒～否则不得装运其它物品。船运时～配装位置应远离卧室、厨房～并与机舱、电源、火源等部位隔离。公路运输时要按规定路线行驶。 第十五部分 法规信息 法规信息:化学危险物品 安全管理 企业安全管理考核细则加油站安全管理机构环境和安全管理程序安全管理考核细则外来器械及植入物管理 条例 (1987年2月17日国务院发布)～化学危险物品安全管理条例实施细则 (化劳发[1992] 677号)～工作场所安全使用化学品规定 ([1996]劳部发423号)等法规～针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定。 provides venture platform, makes many youth round has venture dream, for national solution has important of employment problem. Relevant departments units carefully to discover, cultivate talent. From the perspective of Dongping, contradiction of rapid economic development and personnel shortages. Currently facing the industry transformation and upgrading, and transform and upgrade traditional industries, is the development of new industries such as tourism, logistics, e-commerce, we still lack a large number of capital operation and management of talents, the lack of technological innovation, technology transfer, product research and development, tourism services and other high-level professional and technical personnel. Especially with theIndustry further develops, the demand is growing. We must stand in the global and strategic height, with a high degree of political responsibility and historical mission, counties implement talent strategies as a major and pressing task to seize good, practical human resource development as industrial counties of the country. Departments at all levels must firmly establish the "talent is wealth, talent is competitive, talent is creativity" concept, fully aware of the extreme importance of talent, the real talent working on the agenda, the primary task of the primary resources to support the development of talent. 2 the construction of enterprisers ' as the starting point, and promote the transformation and