GB_23200_7-2016

1GBICS中华人民共和国国家 标准 excel标准偏差excel标准偏差函数exl标准差函数国标检验抽样标准表免费下载红头文件格式标准下载 GB23200.7—2016代替GB/T19426—2006食品安全国家标准蜂蜜、果汁和果酒中497种农药及相关化学品残留量的测定气相色谱-质谱法Nationalfoodsafetystandards—Determinationof497pesticidesandrelatedchemicalsresiduesinhoney,fruitjuiceandwineGaschromatography-massspectrometry2016-12-18发布2017-06-18实施中华人民共和国国家卫生和 计划 项目进度计划表范例计划下载计划下载计划下载课程教学计划下载 生育委员会中华人民共和国农业部发布国家食品药品监督管理总局GBGB23200.7—2016I目次前言„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„Ⅱ1范围„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„12规范性引用文件„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„13原理„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„14试剂和材料„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„15仪器和设备„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„26试样制备„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„27分析步骤„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„28结果计算和表述„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„39精密度„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„410定量限和回收率„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„„4附录A（ 资料 新概念英语资料下载李居明饿命改运学pdf成本会计期末资料社会工作导论资料工程结算所需资料清单 性附录）497种农药及相关化学品中、英文名称、方法定量限、分组、溶剂选择和混合标准溶液浓度表„„„„„„„„„„„„„„„„„„„„„„„„„„5附录B（资料性附录）497种农药及相关化学品和内标化合物的保留时间、定量离子、定性离子及定量离子与定性离子的比值„„„„„„„„„„„„„„„„„„„„„17附录C（资料性附录）A、B、C、D、E五组农药及相关化学品选择离子监测分组表„„„„„„„32附录D（资料性附录）标准物质在蜂蜜基质中选择离子监测GC-MS图„„„„„„„„„„„„„36附录E（资料性附录）实验室内的相对标准偏差„„„„„„„„„„„„„„„„„„„„„41附录F（资料性附录）实验室间的相对标准偏差„„„„„„„„„„„„„„„„„„„„„42附录G（资料性附录）样品的添加浓度及回收率的实验数据„„„„„„„„„„„„„„„„43GB23200.7—2016II前言本标准代替GB/T19426-2006《蜂蜜、果汁和果酒中497种农药及相关化学品残留量的测定气相色谱-质谱法》。本标准与GB/T19426-2006相比，主要变化如下：—标准文本格式修改为食品安全国家标准文本格式；—标准范围中增加“其它食品可参照执行”。本标准所代替标准的历次版本发布情况为：—GB/T19426-2006。GB23200.7—20161食品安全国家标准蜂蜜、果汁和果酒中497种农药及相关化学品残留量的测定气相色谱-质谱法1范围本标准 规定 关于下班后关闭电源的规定党章中关于入党时间的规定公务员考核规定下载规定办法文件下载宁波关于闷顶的规定 了蜂蜜、果汁和果酒中497种农药及相关化学品（参见附录A）残留量气相色谱-质谱测定方法。本标准适用于蜂蜜、果汁和果酒中497种农药及相关化学品残留量的测定，其它食品可参照执行。2规范性引用文件下列文件对于本文件的应用是必不可少的。凡是注日期的引用文件，仅所注日期的版本适用于本文件。凡是不注日期的引用文件，其最新版本（包括所有的修改单）适用于本文件。GB2763食品安全国家标准食品中农药最大残留限量GB/T6682分析实验室用水规格和试验方法3原理试样用二氯甲烷提取，经串联Envi-Carb1）和Sep-Pak-NH22）柱净化，用乙腈-甲苯溶液（3+1）洗脱农药及相关化学品，用气相色谱-质谱仪 检测 工程第三方检测合同工程防雷检测合同植筋拉拔检测方案传感器技术课后答案检测机构通用要求培训 。4试剂和材料除另有规定外，所有试剂均为分析纯，水为符合GB/T6682中规定的一级水。4.1试剂4.1.1乙腈（CH3CN，75-05-8）：色谱纯。4.1.2丙酮(CH3COCH3，67-64-1)：色谱纯。4.1.3二氯甲烷（CH2Cl2，75-09-2）：色谱纯。4.1.4无水硫酸钠（Na2SO4，7757-82-6）：分析纯。用前在650℃灼烧4h，贮于干燥器中，冷却后备用。4.1.5甲苯（C7H8，108-88-3）：优级纯。4.1.6正己烷（C6H14，110-54-3）：色谱纯。4.2标准品农药及相关化学品标准物质：纯度≥95%，参见附录A。4.3标准溶液配制4.3.1标准储备溶液分别称取5mg~10mg（精确至0.1mg）农药及相关化学品各标准物分别于50mL烧杯中，根据标准物的溶解性选甲苯、甲苯-丙酮混合液、二氯甲烷等溶剂溶解，转移到10mL容量瓶中，分别用相应的试剂或溶液定容至刻度（溶剂选择参见附录A），标准溶液避光4℃保存，保存期为一个月。4.3.2混合标准溶液（混合标准溶液A、B、C、D和E）按照农药及相关化学品的保留时间，将497种农药及相关化学品分成A、B、C、D、E五个组，并根据每种农药及相关化学品在仪器上的响应灵敏度，确定其在混合标准溶液中的质量浓度。本标准对497种农药及相关化学品的分组及其混合标准溶液质量浓度参见附录A。依据每种农药及相关化学品的分组号、混合标准溶液质量浓度及其标准储备液的质量浓度，移取一定量的单个农药及相关化学品标准储备溶液于100mL容量瓶中，用甲苯定容至刻度。混合标准溶液GB23200.7—20162避光4℃保存，保存期为一个月。4.3.3内标溶液准确称取3.5mg环氧七氯于50mL烧杯中，用甲苯溶解后转移入100mL容量瓶中，用甲苯定容至刻度。4.3.4基质混合标准工作溶液将40μL内标溶液（4.3.3）和一定体积的混合标准溶液分别加到1.0mL的样品空白基质提取液中，混匀，配成基质混合标准工作溶液A、B、C、D和E。基质混合标准工作溶液应现用现配。4.4材料4.4.1Envi-Carb柱：6mL，0.5g或相当者。4.4.2Sep-Pak-NH2柱：3mL，0.5g或相当者。5仪器和设备5.1气相色谱-质谱仪：配有电子轰击源（EI）。5.2分析天平：感量0.01g和0.0001g。5.3鸡心瓶：200mL。5.4移液器：1mL。5.5具塞锥形瓶：250mL。5.6分液漏斗：250mL。5.7筒形漏斗。6试样制备对无结晶的蜂蜜样品，将其搅拌均匀。对有结晶的样品，在密闭情况下，置于不超过60℃的水浴中温热，振荡，待样品全部融化后搅匀，迅速冷却至室温。分出0.5kg作为试样，置于样品瓶中，密封，并标明标记。果汁、果酒样品，将取得的全部原始样品倒入洁净的搪瓷混样桶内，充分搅拌混匀，再将混匀样品分装出两份（每份500mL），密封，作为试样，标明标记。7分析步骤7.1提取称取15g试样（精确至0.01g）于250mL具塞锥形瓶中，加入30mL水，于40℃振荡水浴上，振荡溶解15min。加入10mL丙酮，然后将瓶中内容物移入250mL分液漏斗中，用40mL二氯甲烷分数次洗涤锥形瓶，并将洗液倒入分液漏斗中，振摇八次，小心排气，静置分层，将下层有机相通过装有无水硫酸钠的筒形漏斗，收集于200mL鸡心瓶中。再依次加入5mL丙酮和40mL二氯甲烷于分液漏斗中，振摇1min，静置、分层后收集。如此重复提取两次，合并提取液，将提取液于40℃水浴旋转蒸发至约1mL，待净化。7.2净化在Envi-Carb柱中加入约2cm高无水硫酸钠，将该柱连接在Sep-Pak-NH2柱顶部，并将串联柱放入下接鸡心瓶的固定架上。加样前先用4mL乙腈-甲苯溶液预洗柱，当液面到达硫酸钠的顶部时，迅速将样品提取液转移至净化柱上，再用3×2mL乙腈-甲苯溶液洗涤样液瓶，并将洗液移入柱中。在串联柱上加上50mL贮液器，用25mL乙腈-甲苯溶液洗脱农药及相关化学品，收集Envi-Carb柱是SUPELCO公司产品的商品名称，给出这一信息是为了方便本标准的使用者，并不是表示对该产品的认可。如果其他等效产品具有相同的效果，则可使用这些等效产品。Sep-Pak-NH2柱是Waters公司产品的商品名称，给出这一信息是为了方便本标准的使用者，并不是表示对该产品的认可。如果其他等效产品具有相同的效果，则可使用这些等效产品。GB23200.7—20163所有流出物于鸡心瓶中，并在40℃水浴中旋转浓缩至约0.5mL。用2×5mL正己烷进行溶剂交换两次，最后使样液体积约为1mL，加入40μL内标溶液，混匀，用于气相色谱-质谱测定。7.3测定7.3.1气相色谱-质谱参考条件a)色谱柱：DB-1701（30m×0.25mm×0.25μm）石英毛细管柱或相当者；b)色谱柱温度：40℃保持1min，然后以30℃/min程序升温至130℃，再以5℃/min升温至250℃，再以10℃/min升温至300℃，保持5min；c)载气：氦气，纯度≥99.999%，流速：1.2mL/min；d)进样口温度：290℃；e)进样量:1μL；f)进样方式：无分流进样，1.5min后开阀；g)电子轰击源：70eV；h)离子源温度：230℃；i)GC-MS接口温度：280℃；j)选择离子监测：497种农药及相关化学品根据保留时间分为A、B、C、D、E五组，每种化合物分别选择一个定量离子，2个~3个定性离子。每组所有需要检测的离子按照出峰顺序，分时段分别检测。每种化合物的保留时间、定量离子、定性离子及定量离子与定性离子的丰度比值，参见附录B。每组检测离子的开始时间和驻留时间参见附录C。7.3.2定性测定样品提取液按照气相色谱-质谱测定条件分别测定A、B、C、D、E五组。进行样品测定时，如果检出的色谱峰的保留时间与标准样品相一致，并且在扣除背景后的样品质谱图中，所选择的离子均出现，而且所选择的离子丰度比与标准样品的离子丰度比相一致（相对丰度＞50％，允许±10％偏差；相对丰度＞20％～50％，允许±15％偏差；相对丰度＞10％～20％，允许±20％偏差；相对丰度≤10％，允许±50％偏差），则可判断样品中存在这种农药或相关化学品。如果不能确证，应重新进样，以扫描方式（有足够灵敏度）或采用增加其他确证离子的方式或用其他灵敏度更高的分析仪器来确证。7.3.3定量测定本方法采用内标法单离子定量测定，内标物为环氧七氯。定量用标准应采用基质混合标准工作溶液。标准溶液的质量浓度应与待测化合物的质量浓度相近。本方法的A、B、C、D、E五组标准物质在蜂蜜基质中选择离子监测GC-MS图参见附录D。7.4平行试验按以上步骤对同一试样进行平行试验测定。7.5空白试验除不称取试样外，均按上述步骤进行。8结果计算和表述气相色谱-质谱测定结果可由计算机按内标法自动计算，也可按式(1)计算：X＝Cs×A×Ci×Asi×V×1000„„„„„„（1）AsCsiAim1000式中：X试样中被测物残留量，单位为毫克每千克（mg/kg）；Cs基质标准工作溶液中被测物的浓度，单位为微克每毫升（µg/mL）；A试样溶液中被测物的色谱峰面积；As基质标准工作溶液中被测物的色谱峰面积；Ci试样溶液中内标物的浓度，单位为微克每毫升（µg/mL）；GB23200.7—20164Csi基质标准工作溶液中内标物的浓度，单位为微克每毫升（µg/mL）；Asi基质标准工作溶液中内标物的色谱峰面积；Ai试样溶液中内标物的色谱峰面积；V样液最终定容体积，单位为毫升（mL）；m试样溶液所代表试样的质量，单位为克（g）。计算结果应扣除空白值，测定结果用平行测定的算术平均值表示，保留两位有效数字。9精密度9.1在重复性条件下获得的两次独立测定结果的绝对差值与其算术平均值的比值（百分率），应符合附录E的要求。9.2在再现性条件下获得的两次独立测定结果的绝对差值与其算术平均值的比值（百分率），应符合附录F的要求。10定量限和回收率10.1定量限本方法的定量限见附录A。10.2回收率当添加水平为LOQ、2×LOQ、5×LOQ时,添加回收率参见附录G。GB23200.7—20165附录A（资料性附录）497种农药及相关化学品中、英文名称、方法定量限、分组、溶剂选择和混合标准溶液浓度表A.1497种农药及相关化学品中、英文名称、方法定量限、分组、溶剂选择和混合标准溶液浓度见表A.1。表A.1序号中文名称英文名称定量限溶剂混合标准溶液质量浓度mg/Lmg/kg内标环氧七氯Heptachlor-epoxide甲苯A组1二丙烯草胺Allidochlor0.066甲苯52烯丙酰草胺Dichlormid0.034甲苯2.53土菌灵Etridiazol0.100甲苯7.54氯甲硫磷Chlormephos0.066甲苯55苯胺灵Propham0.034甲苯2.56环草敌Cycloate0.034甲苯2.57联苯二胺Diphenylamine0.034甲苯2.58杀虫脒Chlordimeform0.034正己烷2.59乙丁烯氟灵Ethalfluralin0.132甲苯1010甲拌磷Phorate0.034甲苯2.511甲基乙拌磷Thiometon0.034甲苯2.512五氯硝基苯Quintozene0.066甲苯513脱乙基阿特拉津Atrazine-desethyl0.034甲苯+丙酮(8+2)2.514异噁草松Clomazone0.034甲苯2.515二嗪磷Diazinon0.034甲苯2.516地虫硫磷Fonofos0.034甲苯2.517乙嘧硫磷Etrimfos0.034甲苯2.518西玛津Simazine0.160甲醇2.519胺丙畏Propetamphos0.034甲苯2.520仲丁通Secbumeton0.034甲苯2.521除线磷Dichlofenthion0.034甲苯2.522炔丙烯草胺Pronamide0.034甲苯+丙酮(9+1)2.523兹克威Mexacarbate0.100甲苯7.524乐果Dimethoate0.132甲苯1025艾氏剂Aldrin0.066甲苯526氨氟灵Dinitramine0.132甲苯1027皮蝇磷Ronnel0.066甲苯528扑草净Prometryne0.034甲苯2.529环丙津Cyprazine0.034甲苯+丙酮(9+1)2.530百菌清Chlorothalonil0.066甲苯531乙烯菌核利Vinclozolin0.034甲苯2.532β-六六六Beta-HCH0.034甲苯2.533甲霜灵Metalaxyl0.100甲苯7.534毒死蜱Chlorpyrifos(-ethyl)0.034甲苯2.5GB23200.7—20166表A.135甲基对硫磷Methyl-Parathion0.132甲苯1036蒽醌Anthraquinone0.034二氯甲烷2.537δ-六六六Delta-HCH0.066甲苯538倍硫磷Fenthion0.034甲苯2.539马拉硫磷Malathion0.132甲苯1040杀螟硫磷Fenitrothion0.066甲苯541对氧磷Paraoxon-ethyl0.066甲苯1042三唑酮Triadimefon0.034甲苯543对硫磷Parathion0.066甲苯1044二甲戊灵Pendimethalin0.022甲苯1045利谷隆Linuron0.066甲苯+丙酮(9+1)10表A.1（续）序号中文名称英文名称定量限溶剂混合标准溶液浓度（mg/L）(mg/kg)46杀螨醚Chlorbenside0.034甲苯547乙基溴硫磷Bromophos-ethyl0.016甲苯2.548喹硫磷Quinalphos0.016甲苯2.549反式氯丹trans-Chlordane0.012甲苯2.550稻丰散Phenthoate0.034甲苯551吡唑草胺Metazachlor0.020甲苯7.552苯硫威fenothiocarb0.012丙酮053丙硫磷Prothiophos0.016甲苯2.554灭菌丹Folpet0.200甲苯3055整形醇Chlorflurenol0.010甲苯+丙酮(9+1)7.556狄氏剂Dieldrin0.034甲苯557腐霉利Procymidone0.016甲苯2.558杀扑磷Methidathion0.022甲苯559氰草津Cyanazine0.026甲苯+丙酮(8+2)7.560敌草胺Napropamide0.020甲苯7.561噁草酮Oxadiazone0.016甲苯2.562苯线磷Fenamiphos0.034甲苯7.563杀螨氯硫Tetrasul0.008甲苯2.564杀螨特Aramite0.008二氯甲烷2.565乙嘧酚磺酸酯Bupirimate0.012甲苯2.566萎锈灵Carboxin0.010甲苯7.567氟酰胺Flutolanil0.008甲苯2.568p,p’-滴滴滴4,4'-DDD0.008甲苯2.569乙硫磷Ethion0.016甲苯570硫丙磷Sulprofos0.014甲苯571乙环唑Etaconazole0.024甲苯7.572腈菌唑Myclobutanil0.016甲苯2.573禾草灵Diclofop-methyl0.008甲苯2.574丙环唑Propiconazole0.024甲苯7.5GB23200.7—20167表A.175丰索磷Fensulfothion0.022甲苯576联苯菊酯Bifenthrin0.012正己烷2.577丁硫克百威Carbosulfan0.020甲苯7.578灭蚁灵Mirex0.008甲苯2.579麦锈灵Benodanil0.016甲苯7.580氟苯嘧啶醇Nuarimol0.014甲苯+丙酮(9+1)581甲氧滴滴涕Methoxychlor0.016甲苯2.582噁霜灵Oxadixyl0.016甲苯2.583胺菊酯Tetramethirn0.014甲苯584戊唑醇Tebuconazole0.024甲苯7.585氟草敏Norflurazon0.016甲苯+丙酮(9+1)2.586哒嗪硫磷Pyridaphenthion0.016甲苯2.587亚胺硫磷Phosmet0.016甲苯588三氯杀螨砜Tetradifon0.012甲苯2.589氧化萎锈灵Oxycarboxin0.024甲苯+丙酮(9+1)1590顺式-氯菊酯cis-Permethrin0.016甲苯2.591反式-氯菊酯trans-Permethrin0.016甲苯2.592吡菌磷Pyrazophos0.014甲苯593氯氰菊酯Cypermethrin0.050甲苯7.594氰戊菊酯Fenvalerate0.034甲苯1095溴氰菊酯Deltamethrin0.100甲苯15B组96茵草敌EPTC0.024甲苯7.597丁草敌Butylate0.024甲苯7.598敌草腈Dichlobenil0.002甲苯0.599克草敌Pebulate0.024甲苯7.5100三氯甲基吡啶Nitrapyrin0.050甲苯7.5101速灭磷Mevinphos0.034甲苯5102氯苯甲醚Chloroneb0.016甲苯2.5103四氯硝基苯Tecnazene0.034甲苯5104庚烯磷Heptanophos0.050甲苯7.5105六氯苯Hexachlorobenzene0.016甲苯2.5106灭线磷Ethoprophos0.050甲苯7.5107毒草胺Propachlor0.024甲苯7.5108燕麦敌cisandtrans-Diallate0.034甲苯5109氟乐灵Trifluralin0.034甲苯5110氯苯胺灵Chlorpropham0.034甲苯5111治螟磷Sulfotep0.016甲苯2.5112菜草畏Sulfallate0.034甲苯5113α-六六六Alpha-HCH0.034甲苯2.5114特丁硫磷Terbufos0.034甲苯5115特丁通Terbumeton0.024甲苯7.5116环丙氟灵Profluralin0.066甲苯10117敌噁磷Dioxathion0.136甲苯10GB23200.7—20168表A.1118扑灭津Propazine0.016甲苯2.5119氯炔灵Chlorbufam0.066甲苯5120氯硝胺Dicloran0.066甲苯+丙酮(9+1)5121特丁津Terbuthylazine0.016甲苯2.5122绿谷隆Monolinuron0.066甲苯10123氟虫脲Flufenoxuron0.100甲苯+丙酮(8+2)7.5124杀螟腈Cyanophos0.066甲苯5125甲基毒死蜱Chlorpyrifos-methyl0.016甲苯2.5126敌草净Desmetryn0.016甲苯2.5127二甲草胺Dimethachlor0.020甲苯7.5128甲草胺Alachlor0.050甲苯7.5129甲基嘧啶磷Pirimiphos-methyl0.016甲苯2.5130特丁净Terbutryn0.034甲苯5131杀草丹Thiobencarb0.034甲苯5132丙硫特普Aspon0.034甲苯5133三氯杀螨醇Dicofol0.034甲苯5134异丙甲草胺Metolachlor0.016甲苯2.5135氧化氯丹Oxy-chlordane0.034甲苯2.5136嘧啶磷Pirimiphos-ethyl0.034甲苯5137烯虫酯Methoprene0.066甲苯10138溴硫磷Bromofos0.034甲苯5139苯氟磺胺Dichlofluanid0.100甲苯15140乙氧呋草黄Ethofumesate0.034甲苯5141异丙乐灵Isopropalin0.034甲苯5142硫丹IEndosulfanI0.100甲苯15143敌稗Propanil0.034甲苯+丙酮(9+1)5144异柳磷Isofenphos0.034甲苯5145育畜磷Crufomate0.100甲苯15146毒虫畏cisandtrane-Chlorfenvinphos0.050甲苯7.5147顺式-氯丹cis-Chlordane0.034甲苯5148甲苯氟磺胺Tolylfluanide0.050甲苯7.5149p,p’-滴滴伊4,4’-DDE0.016甲苯2.5150丁草胺Butachlor0.034甲苯5151乙菌利Chlozolinate0.034甲苯5152巴毒磷Crotoxyphos0.100甲苯15153碘硫磷Iodofenphos0.034甲苯5154杀虫畏Tetrachlorvinphos0.050甲苯7.5155氯溴隆Chlorbromuron0.408甲苯60156丙溴磷Profenofos0.100甲苯15157氟咯草酮Fluorochloridone0.034甲苯5158噻嗪酮Buprofezin0.034甲苯5159o,p’-滴滴滴2,4’-DDD0.016甲苯2.5160异狄氏剂Endrin0.200甲苯30161己唑醇Hexaconazole0.100甲苯15GB23200.7—20169表A.1162杀螨酯Chlorfenson0.034甲苯5163o,p’-滴滴涕2,4'-DDT0.034甲苯5164多效唑Paclobutrazol0.050甲苯7.5165盖草津Methoprotryne0.050甲苯7.5166抑草蓬Erbon0.034甲苯2.5167丙酯杀螨醇Chloropropylate0.016甲苯2.5168麦草氟甲酯Flamprop-methyl0.016甲苯2.5169除草醚Nitrofen0.100甲苯15170乙氧氟草醚Oxyfluorfen0.066甲苯10171虫螨磷Chlorthiophos0.050甲苯7.5172麦草氟异丙酯Flamprop-Isopropyl0.016甲苯2.5173p,p’-滴滴涕4,4’-DDT0.034甲苯5174三硫磷Carbofenothion0.034甲苯5175苯霜灵Benalaxyl0.016甲苯2.5176敌瘟磷Edifenphos0.034甲苯5177三唑磷Triazophos0.050甲苯7.5178苯腈膦Cyanofenphos0.016甲苯2.5179氯杀螨砜Chlorbensidesulfone0.034甲苯5180硫丹硫酸盐Endosulfan-Sulfate0.050甲苯7.5181溴螨酯Bromopropylate0.034甲苯5182新燕灵Benzoylprop-ethyl0.050甲苯7.5183甲氰菊酯Fenpropathrin0.034甲苯5184敌菌丹Captafol0.600甲苯+丙酮(8+2)45185溴苯膦Leptophos0.034甲苯5186苯硫膦EPN0.066甲苯10187环嗪酮Hexazinone0.024甲苯7.5188甲羧除草醚Bifenox0.034甲苯5189伏杀硫磷Phosalone0.034甲苯5190保棉磷Azinphos-methyl0.100甲苯15191氯苯嘧啶醇Fenarimol0.034甲苯5192益棉磷Azinphos-ethyl0.034甲苯5193咪鲜胺Prochloraz0.100甲苯15194蝇毒磷Coumaphos0.100甲苯15195氟氯氰菊酯Cyfluthrin0.200甲苯30196氟胺氰菊酯Fluvalinate0.100甲苯30C组197敌敌畏Dichlorvos0.034甲醇15198联苯Biphenyl0.008甲苯2.5199霜霉威Propamocarb0.100甲苯7.5200灭草敌Vernolate0.016甲苯2.52013,5-二氯苯胺3,5-Dichloroaniline0.016甲苯2.5202禾草敌Molinate0.016甲苯2.5203虫螨畏Methacrifos0.016甲苯2.5204邻苯基苯酚2-Phenylphenol0.008甲苯2.5GB23200.7—201610表A.1205四氢邻苯二甲酰亚胺Tetrahydrophthalimide0.050甲苯7.5206仲丁威Fenobucarb0.016甲苯5207乙丁氟灵Benfluralin0.016甲苯2.5208氟铃脲Hexaflumuron0.100甲苯15209扑灭通Prometon0.016甲苯7.5210野麦畏Triallate0.016甲苯5211嘧霉胺Pyrimethanil0.008甲苯2.5212林丹Gamma-HCH0.016甲苯5213乙拌磷Disulfoton0.016甲苯2.5214莠去净Atrizine0.016甲苯+丙酮(9+1)2.5215七氯Heptachlor0.050甲苯7.5216异稻瘟净Iprobenfos0.034甲苯7.5217氯唑磷Isazofos0.034甲苯5218三氯杀虫酯Plifenate0.034甲苯5219丁苯吗啉Fenpropimorph0.012甲苯2.5220四氟苯菊酯Transfluthrin0.016甲苯2.5221氯乙氟灵Fluchloralin0.066甲苯10222甲基立枯磷Tolclofos-methyl0.016甲苯2.5223异丙草胺Propisochlor0.012甲苯2.5224莠灭净Ametryn0.034甲苯7.5225西草净Simetryn0.016甲苯5226溴谷隆Metobromuron0.100甲苯15227嗪草酮Metribuzin0.034甲苯7.5228噻节因Dimethipin0.100甲苯7.5229ε-六六六Epsilon-HCH0.034甲醇5230异丙净Dipropetryn0.016甲苯2.5231安硫磷Formothion0.034甲苯5232特草定Terbacil0.034甲苯+丙酮(9+1)5233乙霉威Diethofencarb0.050甲苯15234哌草丹Dimepiperate0.034乙酸乙酯5235生物烯丙菊酯Bioallethrin0.066甲苯10236o,p'-滴滴伊2,4'-DDE0.012甲苯2.5237芬螨酯Fenson0.012甲苯2.5238双苯酰草胺Diphenamid0.012甲苯2.5239氯硫磷Chlorthion0.034甲苯5240炔丙菊酯Prallethrin0.034甲苯7.5241戊菌唑Penconazole0.034甲苯7.5242灭蚜磷Mecarbam0.034甲苯10243四氟醚唑Tetraconazole0.050甲苯7.5244丙虫磷Propaphos0.034甲苯5245氟节胺Flumetralin0.034甲苯5246三唑醇Triadimenol0.050甲苯7.5247丙草胺Pretilachlor0.034甲苯5248醚菌酯Kresoxim-methyl0.012甲苯2.5GB23200.7—201611表A.1249吡氟禾草灵Fluazifop-butyl0.012甲苯2.5250氟啶脲Chlorfluazuron0.050甲苯7.5251乙酯杀螨醇Chlorobenzilate0.012甲苯2.5252烯效唑Uniconazole0.034环己烷5253氟哇唑Flusilazole0.050甲苯7.5254三氟硝草醚Fluorodifen0.066甲苯2.5255烯唑醇Diniconazole0.050甲苯7.5256增效醚Piperonylbutoxide0.012甲苯2.5257炔螨特Propargite0.034甲苯5258灭锈胺Mepronil0.012甲苯2.5259噁唑隆Dimefuron0.066甲苯+丙酮(8+2)10260吡氟酰草胺Diflufenican0.012甲苯2.5261喹螨醚Fenazaquin0.012甲苯2.5262苯醚菊酯Phenothrin0.012甲苯2.5263咯菌腈Fludioxonil0.016甲苯+丙酮(8+2)2.5264苯氧威Fenoxycarb0.040甲苯15265稀禾啶Sethoxydim0.152甲苯22.5266双甲脒Amitraz0.020甲苯7.5267莎稗磷Anilofos0.034甲苯5268氟丙菊酯Acrinathrin0.034甲苯5269高效氯氟氰菊酯Lambda-Cyhalothrin0.016甲苯2.5270苯噻酰草胺Mefenacet0.050甲苯7.5271氯菊酯Permethrin0.016甲苯5272哒螨灵Pyridaben0.012甲苯2.5273乙羧氟草醚Fluoroglycofen-ethyl0.100甲苯30274联苯三唑醇Bitertanol0.020甲苯7.5275醚菊酯Etofenprox0.008甲苯2.5276噻草酮Cycloxydim0.080甲苯30277顺式-氯氰菊酯Alpha-Cypermethrin0.016甲苯5278氟氰戊菊酯Flucythrinate0.034环己烷5279S-氰戊菊酯Esfenvalerate0.066甲苯10280苯醚甲环唑Difenoconazole0.066甲苯15281丙炔氟草胺Flumioxazin0.034环己烷5282氟烯草酸Flumiclorac-pentyl0.034甲苯5D组283甲氟磷Dimefox0.026甲苯7.5284乙拌磷亚砜Disulfoton-Sulfoxide0.016甲苯5285五氯苯Pentachlorobenzene0.008甲苯2.5286三异丁基磷酸盐Tri-Iso-ButylPhosphate0.008甲苯2.5287鼠立死Crimidine0.008甲苯2.52884-溴-3,5-二甲苯基-N-甲基氨基甲酸酯-1BDMC-10.016甲苯5289燕麦酯Chlorfenprop-Methyl0.008甲苯2.5290虫线磷Thionazin0.008甲苯2.5GB23200.7—201612表A.12912,3,5,6-四氯苯胺2,3,5,6-Tetrachloroaniline0.008甲苯2.5292三正丁基磷酸盐Tri-N-ButylPhosphate0.016甲苯52932,3,4,5-四氯甲氧基苯2,3,4,5-Tetrachloroanisole0.008甲苯2.5294五氯甲氧基苯Pentachloroanisole0.008甲苯2.5295牧草胺Tebutam0.016甲苯5296蔬果磷Dioxabenzofos0.084甲苯25297甲基苯噻隆Methabenzthiazuron0.084甲苯+丙酮（9+1）25298西玛通Simeton0.016甲苯5299阿特拉通Atratone0.008甲苯2.5300脱异丙基莠去津Desisopropyl-Atrazine0.066甲苯+丙酮（8+2）20301特丁硫磷砜TerbufosSulfone0.008甲苯2.5302七氟菊酯Tefluthrin0.008甲苯2.5303溴烯杀Bromocylen0.008甲苯2.5304草达津Trietazine0.008甲苯2.5305氧乙嘧硫磷Etrimfosoxon0.008甲苯2.5306环莠隆Cycluron0.026甲苯7.53072,6-二氯苯甲酰胺2,6-dichlorobenzamide0.016甲苯+丙酮（8+2）53082,4,4’-三氯联苯DE-PCB280.008甲苯2.53092,4,5-三氯联苯DE-PCB310.008甲苯2.5310脱乙基另丁津Desethyl-Sebuthylazine0.016甲苯+丙酮（8+2）53112,3,4,5-四氯苯胺2,3,4,5-Tetrachloroaniline0.016甲苯5312合成麝香MuskAmbrette0.008甲苯2.5313二甲苯麝香MuskXylene0.008甲苯2.5314五氯苯胺Pentachloroaniline0.008甲苯2.5315叠氮津Aziprotryne0.066甲苯20316另丁津Sebutylazine0.008甲苯+丙酮（8+2）2.5317丁咪酰胺Isocarbamid0.042甲苯+丙酮（8+2）12.53182,2’,5,5’-四氯联苯DE-PCB520.008甲苯2.5319麝香MuskMoskene0.008甲苯2.5320苄草丹Prosulfocarb0.008甲苯2.5321二甲吩草胺Dimethenamid0.008甲苯2.5322氧皮蝇磷FenchlorphosOxon0.016甲苯53234-溴-3,5-二甲苯基-N-甲基氨基甲酸酯-2BDMC-20.016甲苯5324甲基对氧磷Paraoxon-Methyl0.016甲苯5325庚酰草胺Monalide0.016甲苯5326西藏麝香MuskTibeten0.008甲苯2.5327碳氯灵Isobenzan0.008甲苯2.5328八氯苯烯Octachlorostyrene0.008甲苯2.5329嘧啶磷Pyrimitate0.008甲苯2.5330异艾氏剂Isodrin0.008甲苯2.5331丁嗪草酮Isomethiozin0.016甲苯5332毒壤磷Trichloronat0.008甲苯2.5333敌草索Dacthal0.008甲苯2.5GB23200.7—201613表A.13344,4-二氯二苯甲酮4,4-Dichlorobenzophenone0.008甲苯2.5335酞菌酯Nitrothal-Isopropyl0.016甲苯5336麝香酮MuskKetone0.008甲苯2.5337吡咪唑Rabenzazole0.008甲苯2.5338嘧菌环胺Cyprodinil0.008甲苯2.5339麦穗宁Fuberidazole0.042甲苯12.5340异氯磷Dicapthon0.042甲苯12.53412,2’,4,5,5’-五氯联苯DE-PCB1010.008甲苯2.53422-甲-4-氯丁氧乙基酯MCPA-butoxyethylester0.008甲苯2.5343水胺硫磷Isocarbophos0.016甲苯5344甲拌磷砜Phoratesulfone0.008甲苯2.5345杀螨醇Chlorfenethol0.008甲苯2.5346反式九氯Trans-nonachlor0.008甲苯2.5347脱叶磷DEF0.016甲苯5348氟咯草酮Flurochloridone0.016甲苯5349溴苯烯磷Bromfenvinfos0.008甲苯+丙酮（8+2）2.5350乙滴涕Perthane0.008甲苯2.53512,3,4,4’,5-五氯联苯DE-PCB1180.008甲苯2.53524,4-二溴二苯甲酮4,4-Dibromobenzophenone0.008甲苯2.5353粉唑醇Flutriafol0.016甲苯+丙酮（9+1）5354地胺磷Mephosfolan0.016甲苯5355乙基杀扑磷Athidathion0.016甲苯53562,2’,4,4’,5,5’-六氯联苯DE-PCB1530.008甲苯2.5357苄氯三唑醇Diclobutrazole0.034甲苯+丙酮（8+2）10358乙拌磷砜Disulfotonsulfone0.016甲苯5359噻螨酮Hexythiazox0.066甲苯203602,2’,3,4,4’,5-六氯联苯DE-PCB1380.008甲苯2.5361威菌磷Triamiphos0.016甲苯5362苄呋菊酯-1Resmethrin-10.016甲苯5363环菌唑Cyproconazole0.008甲苯2.5364苄呋菊酯-2Resmethrin-20.016甲苯5365酞酸苯甲基丁酯Phthalicacid,benzylbutylester0.008甲苯2.5366炔草酸Clodinafop-propargyl0.016甲苯5367倍硫磷亚砜Fenthionsulfoxide0.034甲苯10368三氟苯唑Fluotrimazole0.008甲苯2.5369氟草烟-1-甲庚酯Fluroxypr-1-methylheptylester0.008甲苯2.5370倍硫磷砜Fenthionsulfone0.034甲苯10371三苯基磷酸盐Triphenylphosphate0.008甲苯2.5372苯嗪草酮Metamitron0.084甲苯+丙酮（8+2）253732,2’,3,4,4’,5,5’-七氯联苯DE-PCB1800.008甲苯2.5GB23200.7—201614表A.1374吡螨胺Tebufenpyrad0.008甲苯2.5375解草酯Cloquintocet-mexyl0.008甲苯2.5376环草定Lenacil0.084甲苯+丙酮（8+2）25377糠菌唑-1Bromuconazole-10.016甲苯5378脱溴溴苯磷Desbrom-leptophos0.008甲苯2.5379糠菌唑-2Bromuconazole-20.016甲苯5380甲磺乐灵Nitralin0.084甲苯+丙酮（8+2）25381苯线磷亚砜Fenamiphoss