Designation: B 731 – 96 (Reapproved 2001)
Standard Specification for
60 % Palladium-40 % Silver Electrical Contact Material 1
This standard is issued under the fixed designation B 731; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
This standard has been approved for use by agencies of the Department of Defense.
1. Scope
1.1 This specification covers 60 % palladium-40 % silver
rod, wire, strip, and sheet material for electrical contacts.
2. Referenced Documents
2.1 ASTM Standards:
B 476 Specification for General Requirements forWrought
Precious Metal Electrical Contact Materials 2
3. Manufacture
3.1 Raw materials shall be of such quality and purity that
the finished product will have the properties and characteristics
prescribed in this specification.
3.2 The material shall be finished by such operations (cold
working, heat treating, annealing, turning, grinding, or pick-
ling) as are required to produce the prescribed properties.
4. Chemical Requirements
4.1 Material produced under this specification shall meet the
requirements for chemical composition prescribed in Table 1,
in accordance with the practices prescribed in Specification
B 476.
4.2 Uniformity of composition shall be assured by the use of
good commercial preparation practices.
5. Mechanical Requirements
5.1 The contract or order may specify ultimate tensile
strength, elongation, microhardness (Knoop or Vickers), or a
combination of these mechanical properties (as listed in Table
2 or Table 3) as temper criterion. If the contract or order does
not specify a temper criterion, then the criterion for temper
designation will be ultimate tensile strength.
5.2 All test specimens shall be full thickness or diameter
when practical.
5.3 All tests are to be conducted at room temperature, about
68°F (20°C).
6. Inspection and Testing
6.1 Material furnished under this specification shall be
inspected by the manufacturer in accordance with Specification
B 476.
7. Keywords
7.1 clad materials; contact material; palladium alloy; pre-
cious metal; silver alloy1 This specification is under the jurisdiction of ASTM Committee B02 on
Nonferrous Metals and Alloys and is the direct responsibility of Subcommittee
B2.05 on Precious Metals and Electrical Contact Materials.
Current edition approved May 10, 1996. Published July 1996. Originally
published as B 731 – 84. Last previous edition B 731 – 91.
2 Annual Book of ASTM Standards, Vol 02.04.
TABLE 1 Chemical Composition
Element Weight
Pd (by difference) 59.5 % min.
Ag 39.1 to 40.5 %
Cu 0.1 max
Total other noble metals A 0.2 max
Other Impurities:
Individual elements B 0.01 max
Collective total 0.10 max
A Other noble metals are Au, Pt, Rh, Ir, Ru, and Os.
BTypical metals are as indicated: Pb, Sn, Zn, Fe, Si, Mg, Ca, Al, Ni, Cr, Mn, Sb,
B, Co, Mo, and Te, Cd, and In.
1
Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
APPENDIX
(Nonmandatory Information)
X1. TYPICAL PROPERTY VALUES
X1.1 The following is a list of typical property values that
are useful for engineering calculations in electrical contact
design and application.
Electrical conductivity, % IACS
Resistivity,V· cmil/ft
4
258
Microhm·cm 43
Solidus temperature, °C 1290
Liquidus temperature, °C 1340
Density:
g/cm 3 11.35
tr oz/in. 3 5.98
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in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk
of infringement of such rights, are entirely their own responsibility.
This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and
if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards
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This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,
United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above
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TABLE 2 Mechanical Properties of Sheet and Strip
Temper Reduction in B&S
Numbers
(Reference)
Percent Reduction
(Reference)
Ultimate Tensile Strength, psi (MPa) Minimum Elonga-
tion in 2 in., %
Typical
Microhardness
HK 100gmin max
A 0 0 50 000 (344) 80 000 (551) 30 120
1 / 2 H 2 21 70 000 (482) 90 000 (620) 2 170
Hard 4 37 80 000 (551) 100 000 (180) 1 180
Spring 8 60 90 000 (620) 120 000 (827) ... 200
TABLE 3 Mechanical Properties of Wire, Rod, and Tubing
Temper Reduction in B&S
Numbers
(Reference)
Percent Reduction
(Reference)
Ultimate Tensile Strength, psi (MPa) Minimum Elonga-
tion in 2 in., %
Knoop Hardness
(25 g, load)
min max
A 0 0 40 000 (275) 60 000 (414) 25 A 90–120
1 / 8 H 1 / 2 11 60 000 (414) 70 000 (482) 2 120–140
1 / 4 H 1 21 70 000 (482) 80 000 (551) 1 140–160
1 / 2 H 2 37 80 000 (551) 90 000 (620) 1 160–200
Hard 4 60 90 000 (620) 100 000 (689) 1 200–240
AWire in sizes less than 0.020 in. (0.5 mm) diameter and tubing of less than 0.010 in. (0.25 mm) wall thickness may be down to 15 %.
B 731
2
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