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首页 金属有机化学国家重点实验室2000年年度进展报告- 上海有机化学研究所

金属有机化学国家重点实验室2000年年度进展报告- 上海有机化学研究所.doc

金属有机化学国家重点实验室2000年年度进展报告- 上海有机化…

压力下滴男人
2017-12-20 0人阅读 举报 0 0 暂无简介

简介:本文档为《金属有机化学国家重点实验室2000年年度进展报告- 上海有机化学研究所doc》,可适用于工程科技领域

金属有机化学国家重点实验室年年度进展报告上海有机化学研究所二年重大事记一完成,年基金申请共资助了个项目,其中有机所个,外单位个,资助总额万。二,实验室换届工作根据中国科学院厅局文件关于印发<<中国科学院开放实验室主任、学术委员会主任聘任办法>>的通知和关于年开放实验室换届工作的通知,在院、所领导支持下和上一届全体学术委员的配合下,我们顺利地完成了今年的换届工作。本届实验室主任为麻生明研究员,学术委员会主任为钱长涛研究员。三引进年轻的跨世纪学术带头人为了建立一支稳定流动的高水平的青年人才队伍,开放室在人才引进工作上一直采取专家推荐与实验室主动联系的方式积极引进人才。为了实验室的进一步发展,今年又分别从国外和国内引进名青年学术带头人张兆国博士和许旭博士。四知识创新工程的实施和检查我室今年在有机所领导的支持下,知识创新工程的各项工作进展良好。为了进一步推进知识创新工程全面、深入的开展,中科院高技术局实验室处邢如云处长、李刚同志于月日到有机所,调研我们所金属有机化学开放实验室在创新工程中有关科技目标的凝练和改革方案中节点目标的执行情况。到会的有有机所所长郑崇直、副所长吕龙、科研处处长姚祝军、副处长陈维明、财务处处长傅丽英以及金属有机开放室的陆熙炎院士、戴立信院士等全体学科带头人。首先实验室主任麻生明研究员汇报了开放实验室知识创新工程执行情况。接着全体到会人员就实验室的知识创新工作进行了热烈具体的讨论。所领导肯定了实验室全体人员的努力,同时表明有机所在知识创新工程中将继续支持开放室的进一步发展。院领导主要了解了开放室知识创新工作中科技目标的凝练和结构的调整,了解我们开放室创新经费的使用情况,尤其是如何建立合适的分配激励制度,最大限度发挥每个学术带头人的专长和工作积极性。大家就目前遇到的问题进行充分的交流,达成共识,为下一步知识创新工作的更好完成打下扎实的基础。月日,侯雪龙副主任又到北京参加中科院召开的“重点实验室试点工作总结交流会”,并代表金属开放室在会上作了实验室工作汇报。会上到会的各进入知识创新工程的实验室进行了充分交流,讨论如何做好下一步的知识创新工作。五项目的启动经过努力,由我室麻生明研究员作为首席科学家之一的项目“创造新物质的分子工程学研究”于今年正式启动,月日在上海有机所召开了项目的启动会议,年底由我们开放室成员参与的两个子课题的经费已经到位。我们将努力高质量的尺寸的稀土金属和稀土氢化物粉末、高选择性有机合成反应中双金属催化的协同效应宋礼成南开大学两类单蝶状铁硫络盐的新反应及其在合成多蝶状簇合物中的应用研究黄宪浙江大学,杂原子或金属取代的,、,不饱和砜及膦酸脂的合成及其在立体选择合成反应中的应用沈琪苏州大学稀土和后过渡金属化合物的合成及催化聚合活性的研究康北笙中山大学含咪唑基三角架型氮杂化合物的亲金属性研究沈之荃浙江大学钐化合物催化极性单体聚合研究张永敏浙江大学稀土金属和过渡金属试剂在有机合成中的应用张良辅成都有机所多相不对称催化反应的研究刘汉范北化所纳米金属簇催化酮酸酯及二酮的不对称氢化其对催化反应的影响王积涛南开大学金属有机试剂在,氨基酸手性合成中的的应用徐善生南开大学单桥及双桥连二环戊二烯基双核过渡金属化合物的研究周其林南开大学螺旋型手性催化剂的设计合成及其应用性研究曹卫国上海大学胂叶立德在高选择性合成中的应用――立体选择性合成γ丁内酯及γ丁内酰胺类化合物周锡庚复旦大学炔丙基稀土金属有机物的合成、结构及其反应席振峰北京大学过渡金属促进的利用二氧化碳作为碳源的新型碳,碳键形成反应江焕峰广化所过渡金属化合物在超临界二氧化碳介质中的催化行为研究庞震复旦大学含半活性配位基团的金属有机配合物的合成及其对催化反应的影响张兆国上海有机所亚胺及烯胺的氢甲酰化反应二年论文目录课题负责人:陆熙炎课题编号:AnEfficientPreparationof,Alkylidene,formylmethyl,lactamsviaPd(II)CatalyzedIntramolecularAlkyne,~,,UnsaturatedCarbonylCouplingXie,XLu,X*Synlett,RoleofHalideIonsinPalladium(II)CatalyzedNucleophileAlkynea,bUnsaturatedCarbonylCouplingReactionsLu,XWang,ZPolyhderon,,EffectofHalideLigandsonthereactivityofCarbonPalladiumBonds:ImplicationsforDesigningCatalyticReactionsWang,ZZhang,ZLu,X*Organometallics,,AFacileHighlyRegioandStereoselectivePreparationofNTosylAllylicAminesfromAllylicAlcoholsandTosylIsocyanateviaPalladium(II)CatalyzedAminopalladation,HeteroatomEliminationLei,ALu,X*OrgLett,,Palladium(II)CatalyzedTandemIntramolecularAminopalladationofAlkynesandConjugateAdditionSynthesisofOxazolidinones,ImidazolidinonesandLactamsLei,ALu,X*OrgLett,,HighlyEnantioselectivePalladium(II)CatalyzedCyclizationof(Z)'Acetoxy'butenylAlkynoatesAnEfficientSynthesisofOpticallyActive,ButyrolactonesZhang,QLu,X*JAmChemSoc,,课题负责人:钱长涛课题编号:CoordinativelyUnsaturatedNeodymiumHydrides,StabilityinSolutionVisseauxMarc,BaudryDenise,DormondAlain,QianChangtaoJOrganometChem,,(),CycloadditionReactionsofImineswithAlkynylSelenidesCatalyzedbyScandiumTriflateYunMaandChangtaoQianTetrahedronLetters,,,AsymmetricHeteroDielsAlderReactionofGlyoxylateEstersandDanishefsky'sDieneCatalyzedbyChiralBis(oxazoline)LanthanideComplexesChangtaoQianandLongchengWangTetrahedronLetters,,,FirstApplicationofAminoTADDOLDerivativesinEnantioselectiveAdditionofDiethylzinctoArylAldehydes:EffectofSubstituentsontheNitrogenAtomChangtaoQian,FeiFengGaoandSunJieTetrahedron:Asymmetry,,,AsymmetricGlyoxylateEneReactionCatalyzedbyCsymmetricChiralBis(Oxazoline)LanthanideComplexesChangtaoQianandLongchengWangTetrahedron:Asymmetry,,,AdditionofSilylKeteneAcetalstoNitronesCatalyzedbyLanthanideTriflatesChangtaoQianandLongchengWangTetrahedron,,,LanthanideTriflateCatalyzedBiginelliReactionOnePotSynthesisofDihydropyrimidinonesunderSolventFreeConditionsYunMa,ChangtaoQian,LiminWangandMinYangJOrgChem,,,CSymmetricansaLanthanocenesDesignedforStereospecificPolymerizationofsMethylMethacrylate,SynthesisandStructuralCharacterizationofSilyleneBridgedFluorenylCyclopentadienylLanthanideHalides,AmidesandHydrocarbylsChangtaoQian,WanliNieandJieSunOrganometallic,,,StereoselectiveSynthesisandStructuralCharacterizationofracPlanarChiralBis(methoxyethylindenyl)lanthanumandYttriumTetrahydroboratesChangTaoQian,GangZou,WanLiNie,JieSun,DmitriALemenovskiiandMaximVBorzovPolyhedron,,,SynthesisandStrctureofBariumComplexContaining,,,Tetramethyl,heptanedionateand,PhenanthrolineLigandsXieMeiHua,QianChangTao,GaoLiJun,SunJieChineseJStructChem,,,SynthesisofFuro,candPyrano,cQuinolinesbyLanthanideTriflateCatalyzedIminoDielsAlderReactionYunMa,ChangtaoQian,MeiHuaXieandSunJieChinJChem,,,后过渡金属催化剂催化乙烯聚合邹丰楼,李阳,邹晓天,宋玉春,钱长涛,陈瑞芳,陆汉章合成树脂及塑料,,(),课题负责人:麻生明课题编号:Stepwise,Brominationof,DihaloalkenesShengmingMa*,BinXu,andShiminZhaoSynthesis,Pd()catalyzedCyclizationReactionofArylorAlkenylHalideswith,DienylKetonesAGeneralandEfficientSynthesisofPolysubstitutedFuransShengmingMa*andJunliangZhangChemCommun,,UnusualRegioselectivityofPd()CatalyzedCouplingReactionofElectrondeficientAlkenylHalideswithAllenicPropargylicZincReagentsHighlySelectiveSynthesisofPhenylhexyn(or)enoatesenitrilesandPhenylsubstitutedhexa,,trienoatesShengmingMa*,AibinZhang,YihuaYu,andWeiXiaJOrgChem,,AlXHOpromotedHydrohalogenationReactionof,AllenicSulfoxidesShengmingMa*andQiWeiEurJOrgChem,Palladium(II)CatalyzedCyclizationReactionofAllylicBromideswith,DienylKetonesAnEfficientSynthesisofAllylicPolysubstitutedFuransShengmingMa*andLintaoLiOrganicLetters,,Palladium()catalyzedCyclizationReactionofPolymerSupportedArylIodideswith,AllenylCarboxylicAcidsAFacileSolidPhaseSynthesisofButenolidesShengmingMa,*DehuiDuan,andZhangjieShiOrganicLetters,,,ReverseofRegioselectivityinIntramolecularNucleophilicSubstitutionof,–AllylPalladiumSpeciesHighlySelectiveFormationofVinylicCyclopropanesviathePd()–CatalyzedCouplingCyclizationReactionofOrganicIodideswith(’,’Dienyl)malonatesShengmingMa*andShiminZhaoOrganicLetters,,EfficientSynthesisof('Alkenyl),dihydrofuransviaPdClcatalyzedCouplingCyclizationReactionof,AllenolswithAllylicHalidesShengmingMa*andWenzhongGaoTetrahedronLett,,StudiesontheOxidativeAdditionReactionof,Dibromoalkenes,,Dehalopalladation,andtheIntramolecularBis(carbopalladation)ReactionofAlkenesAnEfficientEntrytoFusedBicyclesShengmingMa*,BinXu,andBukuoNiJOrgChem,,UniqueSelectivityofIodohydroxylationReactionofAllenylPhenylSulfoxidesinAqueousMeCNAStereodefinedSynthesisof(E)IodohydroxyalkenylSulfoxidesShengmingMa*,QiWei,andHaimingWangOrganicLetters,,UnexpectedFacileSequentialHalolactamizationHydroxylationof,AllenamideswithCuXfortheEfficientSynthesisofHalohydroxypyrrol(H)onesShengmingMa*andHexinXieOrganicLetters,,Review:RecentProgressinCarbolithiationReaction(碳锂化反应的研究进展)BinXuandShengmingMa*ChinJOrgChem(有机化学),,SynthesisandStructureoftheFirstPropellershapedHelicalCoordinationPolymerofAgwithBis(oxazoline)LigandsShengmingMa*andShulinWuChinJChem,,Review:RecentAdvancesinMetamediatedSynthesisofSubstitutedFurans(金属催化合成呋喃衍生物的最新进展)LintaoLiandShengmingMa*ChinJOrgChem(有机化学),,SynthesisandReactionof,AllenylKetones(,联烯基酮的合成与反应)LintaoLiandShengmingMa*ChinJOrgChem(有机化学),,课题负责人:侯雪龙课题编号:RingopeningofNTosylaziridineswithTMSNandTMSCNTriggeredbyTBAF:AnEfficientandConvenientRoutetoVicinalDiaminesand,AminoacidJieWu,XueLongHouandLiXinDaiJOrgChem,,OntheRoleofPlanarChirality:aTunableEnantioselectivityinPalladiumCatalyzedAllylicAlkylationwithPlanarChiral,’P,NferroceneLigandsWeiPingDeng,XueLongHou,LiXinDai,YiHuaYuandWeiXiaChemCommun,Synthesisof(,SubstitutedNTosylaminomethyl),DihydrofuransbyReactionofNSulfonylimineswithArsoniumorSulfoniumHydroxylcisbutenylidesWeiPingDeng,AnHuLi,LiXinDai,andXueLongHouTetrahedron,,SynthesisofPlanarChiralSelenideDerivativesofFerrocenyloxazolineandTheirApplicationinEnantioselectivePalladiumCatalyzedAllylicSubstitutionReactionShuLiYou,XueLongHouandLiXinDaiTetrahedron:Asymmetry,,AStereoselectiveMichaeliminoAldolTandemReactionTriggeredbyThiolateAnionsXiaoFangYang,XueLongHouandLiXinDaiTetrahedronLett,,NovelN,SandN,SePlanarChiral,ParacyclophaneLigands:SynthesisandApplicationinPdCatalyzedAllylicAlkylationXueLongHou,XunWeiWuandLiXinDaiChemCommun,EfficientPlanarChiral,’P,NSubstitutedFerroceneLigandsforAsymmetricHeckReaction:ControlofEnantioselectivityandConfigurationbyPlanarChiralSubstituentWeiPingDeng,XueLongHouandLiXinDaiChemCommun,NovelBisN(diphenylphosphino)ferrocenylcarbonyldiaminocyclohexaneLigands:ApplicationinAsymmetricAllylicAlkylationofIminoEsterwithSimpleAllylCarbonateShuLiYou,XueLongHou,LiXinDai,BoXunCaoandJieSunChemCommun,硫叶立德途径立体控制合成乙烯基型环氧化合物周永贵,李安虎,戴立信,侯雪龙化学学报,,FructoseDerivedPyridylAlcoholLigands:SynthesisandApplicationintheAsymmetricDiethylzincAdditiontoAldehydesYongGuiZhou,LiXinDaiandXueLongHouChineseJChem,,课题负责人:沈延昌课题编号:NovelBasecatalyzedOlefinationMethodologyStereoselectiveSynthesisof(E),benzenesulfinylVinylphosphonatesYanchangShen,GuoFangJiangSynthesis,,SequentialTransformationsofPhosphonates"OnepotSynthesisofEthoxycarbonylAllylSubstitutedOximeEthersYanchangShen,GuoFangJiangSynthesis,,StereocontrolledSynthesisofFluorinatedEorZAllylicPhosphonatesYanchangShen,YumingZhang,ZenghongZhangSynthesis,,StereoselectiveSynthesis(E)Cyano,~,UnsaturatedNitrilesYanchangShen,ZenghongZhangSynthCommun,,AConvenientSynthesisof(E),Cyanoand(E),ethoxycarbonylvinylphosphonatesYanchangShen,GuoFangJiangJChemRes(s),NewSyntheticMethodologiesforCarbonCarbonMultipleBondFormationShenYanchangActaChimicaSinica,,,课题负责人:陈家碧课题编号:ReactionsofCationicCarbyneComplexesofManganeseandRheniumwith(CarbonylmetalAnionsContainingCyclopentadienyl,PPh,andNOLigandsARoutetoDimetalBridgingCarbeneandCarbyneComplexesYongjunTang,JieSu,JiabiChen*Organometallics,,,ReactionsofCationicBridgingCarbyneComplexesofBis(cyclopenta(,dienyl)diironTricarbonylwithNucleophilesARoutetoDiironBridgingCarbeneComplexesYajunLiu,RuitoWang,,JieSu,JiabiChen*Organometallics,,,UnusualReactionsofCationicBridgingCarbyneComplexesofBis(,cyclopentadienyl)diironTricarbonylwithCarbonylmetalAnionsARoutetoDiironBridgingCarbyneComplexesYajunLiu,RuitaoWang,JieSun,andJiabiChen*Organometallics,,,RemarkableTransformtionofThiopheneLigandsinTheirPentamethylcyclopentadienylIridium(Cp*Ir)CoplexesJiabiChen,*RobertJAngeliciCoordinationChemistryReviews,,,ReactionsofDicarbonylcis(:dicyclopentadienyl,,,,,,dimethylsilane)bis(carbonyliron)withAryllithiumReagentsCrystalStructuresofFe(CO){C(OCH)CH}(CO){(CH)Si(CH)},,,andFe(CO){C(OCH)CHOCHp}(CO){(CH)Si(CH)},,,RuitaoWang,JieSun,JiabiChen*JOrganometChem,,,课题负责人:邓敏智课题编号:SilverOxideMediatedPalladiumcatalyzedCrosscouplingReactionofCyclopropylboronicAcidswithAllylicBromidesHanChenandMinzhiDengJOrgChem,,~FacileApproachtosubstituted()HfuranonesMinLiangYaoandMinzhiDengJOrgChem,~ANovelStereocontrolledSynthesisof,transCyclopropylKetonesviaSuzukitypeCouplingofAcidsChlorideswithCyclopylboronicAcidsHanChenandMinzhiDengOrganicLetters,(),~APracticalApproachtoStereodefinedCyclopropylsubstitutedHeteroarenesusingSuzukitypeReactionMinLiangYaoandMinzhiDengNewJChem,,~PalladiumcatalyzedCrosscouplingReactionofCyclopropylboronicAcidswithArylTriflatesMinLiangYaoandMinzhiDengSynthesis,,~ANovelRoutetoStereodefinedCyclopropylsubstitutedAlkenesShaoManZhouandMinzhiDengTetrahedronLetters,,~PalladiumcatalyzedCrosscouplingofCyclopropylboronicAcidswithAlkenylTriflatesMinLiangYaoandMinzhiDengTetrahedronLetters,,~ANovelandConvenientMethodtoSubstitutedCoumarinsMinLiangYaoandMinzhiDengHeteroatomChemistry,(),~ANovelSuzukitypeCrosscouplingReactionofCyclopropylboronicEsterswithBenzylbromidesHanChenandMinzhiDengJChemSocPerkinTransI,~NicklecatalyzedAllylationofLithiumAlkynyl(trialkoxy)borateswith,SubstitutedAllylCarbonatesHanChenandMinzhiDengJOrganometChem,,~课题负责人:姜标课题编号:StereocontrolledSynthesisE,(S)TrifluoromethylSidechainofSteroidandItsApplicationinSynthessisofFluorinatedAnaluguesNaturalOccuringSterolsBJiang,YLiu,ZhouWeishang,JOrgChem,,,,DipolarCyloaddtionofChiallyModifiedVinylboronicEsterwithNtrileOxidesBiaoJiang,AoZhang,YingKan,GuilingZhaoandBiaoJiangTetrahedron,,,CSymmetricBisphoshoineandaBisaminophosphineasNewChiralLigandsforPdcatalyzedAsymmetricAllylicSubstitutionAoZhang,YanFeng,BiaoJiangTetrahedron:Asymmetry,,,SolidPhaseAsymmtricSynthesisofIsoxazolineNingZhou,BiaoJiang,JComChem,,(),SynthesesandCytotoxicityEvaluationofBis(indolyl)thiazole,Bis(indoly)pyrazinoneandBis(indolyl)pyrazine:AnaloguesofCytotoxicMarineBis(indole)AlkaloidBiaoJiang*andXiaoHuiGuBioorganicMedicinalChemistry,,,SynthesesofIndoylpyrimidineviaCrossCouplingofIndolylboronicAcidwithChloropyrimidines:FacileSynthesisofMerdianinDBiaoJiang,CaiguangYangHeterocycles,,(),SynthesesofBis(indolyl)pyrazinoneBiaoJiang,XiaoHuiGuHeterocycles,,(),HighlyEnatiooselectiveReductionofAchralwithNaBHMeSiClCatalyyzedby(S)diphenylpyrrolidinemethyanolBiaoJiang,YanFeng,JianZhengTetrahedronLetters,,,SynthesisofNovelCompatibilizersandTheirApplicationinPPnylonBlendsISynthesisandCharacterizationa,*bacDeLiangXie,DaChen,BiaoJiang,ChangZhengYangPolymer,,,InsituNMRStudyofAsymmetricBoraneReductionReactionanAbnormalFactorintheTemperatureEffectontheBisoxazaborolidineCatalustandtheRelationshipbetweentheCatalystStructureandSelectivityaa,*abJinkaiZhao,XinheBao,XiumeiLiu,andBiaoJiangTetrahedron:Asymmetry,,,Asymmetric,dipolarCyloaddtionofNitrileOxidestoAcryloylEstersDearingGlucofuranoseasAuxiliaryBiaoJiang,AoZhang,YingKan,ChinJChem,,(),新型海洋双吲哚类生物碱的研究进展*谷晓辉姜标,,,有机化学羟基酸引发,己内酯开环聚合的研究解德良,姜标高分子学报,,,TheMechanismofAsymmetricReductionofbyCatalytyzedbyACSymmetricisAminoAlcoholCatalystJinkaiZhao,XiuwenHan,XiumaeiLiu,XinheBao,JianFengHang,andBiaoJiangScienceinChina,,,课题负责人:施敏课题编号:AnUnexpectedCarbonDioxideInsertionintheReactionofTrans,DisubstitutedAzetidine,Trans,DisubstitutedPyrrolidine,orTrans,DisubstitutedPiperidinewithDiphenylthiophosphinicChlorideandDiphenylselenophosphinicChlorideMinShi,*JianKangJiang,YuMeiShen,YanShuFeng,andGuiXinLeiJOrgChem,,,TheCrystallographicStructureofaNovelCamphanicAmideMinShi*andGuiXinLeiJChemCrystallography,,,ChiralDiphenylthiophosphoramides:ANewClassofChiralLigandsfortheSilver(I)PromotedEnantioselectiveAllylationofAldehydesMinShi*andWenShengSuiTetrahedron:Asymmetry,,,ChiralDiphenylselenophosphoramides:aNewClassofChiralLigandsfortheTitanium(IV)AlkoxidepromotedAdditionofDiethylzinctoAldehydesMinShi*andWenShengSuiTetrahedron:Asymmetry,,,AFacileRoutetoBulladecinTypeAcetogeninsTotalSynthesisofAsimilobinandCorrectionofItsTetrahydrofuranSegment'sConfigurationZhiMinWang,*ShiKaiTianandMinShi*EurJOrgChem,,AmendmentinTitanium(IV)ChlorideandChalcogenidePromotedBaylisHillmanReactionofAldehydeswith,~,UnsaturatedKetonesMinShi*andJianKangJiangTetrahedron,,,SynthesisofaNovelChiralRutheniumComplexandItsCrystalStructureMinShi,*KazuyaKobiro,TomomiFujitaJOrganometalChem,,,Titanium(IV)ChlorideandAminepromotedBaylisHillmanReactionMinShi,*JianKangJiangandYanShuFengOrgLett,,,ASimpleSyntheticMethodforChiral,EpoxidesandtheTotalSynthesisofaChiralPheromoneEpoxideZhiBoZhang,ZhiMinWang,*YuXiuWang,HuanQuanLiu,GuiXinLeiandMinShi,JChemSoc,PerkinTrans,,TotalSynthesisofGigantetrocinAZhiMinWang,*ShiKaiTianandMinShi*Chirality,,,Trifluoromethanesulfonamide,DiphenylphosphoramideandDiphenylthiophosphoramideof(R)(),'Binaphthyl,'diamineasChiralCatalystLigandsfortheTitanium(IV)AlkoxidePromotedAdditionofDiethylzinctoAldehydesMinShi*andWenShengSuiChirality,,,TheCrystallographicStructureofhydroxymethylene(pnitrophenyl)butanoneMinShi*andJianKangJiangJChemCrystallography,,,ANewClassofChiralPyrrolidineLigandsforHomogeneousCatalyticEnantioselectiveCyclopropanationofStyreneMinShi*andJianKangJiangChinJChem,,,课题负责人:丁奎岭课题编号:Reductionof,’BinaphthylstoOctahydro,’binaphthylDerivativeswithRaneyNiAlalloyinAqueousSolutionHuiGuo,KuilingDingTetrahedronLett,,,PracticalMethodandNovelMechanismforOpticalResolutionofBINOLbyMolecularComplexationwithNbenzylcinchoniumChlorideYWang,JSun,KuilingDingTetrahedron,,,SynthesisofNovelN,PChiralLigandsforPalladiumcatalyzedAsymmetricAllylation:TheEffectofBinaphthylBackboneontheEnantioselectivityYiWang,HuiGuo,KuilingDingTetrahedron:Asymmetry,Lett,,TheSynthesisofNovelNonCSymmetricHBINOLLigandandItsApplicationtoTitaniumcatalyzedEnantioselectiveAdditionofDiethylzinctoAldehydesXShen,HGuo,KDingTetrahedron:Asymmetry,,,催化不对称反应新进展不对称活化,综述与进展,丁奎岭、林国强有机化学,,,催化不对称反应新进展组合化学方法之应用,综述与进展,丁奎岭有机化学,,,课题负责人:唐勇课题编号:SwitchingofStereoselectivity:DramaticEffectsofHMPAontheStereoselectiviyofCyclopropanationReactionofSilylatedTellroniumAllylidewith,,,UnsaturatedEstersandAmidesYe,STang,Y*Dai,LXJOrgChem,,课题负责人:廖世健课题编号:水滑石选择性催化合成三乙二醇单丁醚刘金龙王永杰廖世健,王复东,徐杰魏同成催化学报,,PVPPd催化六氯苯加氢脱氯中两种氢源的贡献高燕廖世健,徐杰,上官勇刚,顾志祥蹇锡高催化学报,,课题负责人:宋礼成课题编号:SynthesisofDoubleandQuadrupleButterflyFeSClusterComplexesviaaNovelTypeofReactionofAnions(,RS)(,S)Fe(CO)(,S)withSuccinylChlorideLiChengSong,GuoLiangLu,QingMeiHu,andJieSunOrganmetallics,,课题负责人:黄宪课题编号:HydrozirconationofAlkynylSulfoxides:theReactionsofZirconatedVinylSulfoxideIntermediatesPingZhong,XianHuang,MengPingGuoTetrahedron,,,课题负责人:沈琪课题编号:SynthesisofIndenyllanthanideAmides:theEffectiveInitiatorsforPolymerizationofMethylMethacrylateZhaoQun,YaoYingMing,ShenQiChinJChem,,(),课题负责人:康北笙课题编号:ChemistryofAroylhydrazonesIIEnolformCoordinationof,Diazafluoreneonesalicyloylhydrazone(HL)toTransitionMetalsandCrystalStructuresofHL,Mn(HL)(HO)andCo(HL)(DMF)Xiao,W,Lu,ZL,Wang,XJ,Su,CY,Yu,KB,Liu,HQ,Kang,BSPolyhedron,,(),,DiazafluoreneoneAcylhydrazonesandtheirLeadComplexesandtheCrystalStructureofHydrated,DiazafluoreneonemethoxybenzoylhydrazoneupportedbyExtensiveHydrogenBondsandAromaticRing,?S,StackingInteractionsXiao,W,Lu,ZL,Deng,LR,Su,CY,Tong,YX,Liu,HQ,Kang,BSPolishJChem,,,BivalentTransitionMetalComplexesof,DiazofluorenoneBenzoylhydrazone(HL)andtheCharacterizationofWeakInteractionsinCoLHOXiao,W,Lu,ZL,Su,CY,Yu,KB,Deng,LR,Liu,HQ,Kang,BSJMolStru,,,NMRStudieson,DiazafluorenoneNaphthalylhydrazoneanditsLeadComplexXiao,W,Lu,ZL,Kang,BS,Liu,,HQ,Su,CYJChiMagneticResonance,,(),课题负责人:沈之荃课题编号:课题负责人:张永敏课题编号:SamariumDiiodideInducedReductiveCyclizationofNitroCompoundswithKetones:ANovelSynthesisof,Dihydro(H),,Benzothiadiazine,DioxidesWeihuiZhong,XiaoyuanChen,YongminZhang*JChemRes(S),,(),ANewRouteto,Dihydro,BenzothiazepinesfromNiteodisulfidesandα,βUnsaturatedKetonesbySmIXiaoyuanChen,WeihuiZhong,YongminZhangJChemRes(S),,(),SamariumDiiodideMediatedSimultaneousreductionofNitroGroupandtheAzideGroupinoNitrophenylazide:ANewAccessto,DihydroH,BenzodiazepinesWeihuiZhong,YongminZhang*andXiaoyuanChenJChemRes(S),,ANovelMethodforPinacolicCouplingofAromaticAldehydesandKetoneswithaSmZnClSystemHongyunGuo,YongminZhangJChemRes(S),,(),ANovelReductionofoNitrophenoxyCompoundsPromotedbyLowValentTitanium:AnAccessToH,BenzoxaineDerivativesYongminMa,YongminZhanaJChemRes(S),,(),SmSmITiCl(cat)SystemPromotedDirectAlkylidenatingReactionofKetoneswithgemDibromomethylSulfones:ANewMethodforPreparationofAlkylideneSulfonesYunKuiLiu,Yongmin,Zhang*,XiLiuJChemRes(S),,FacileSynthesisofAmidinesviaIntermolecularReductiveCouplingofNitrileswithAzobenzenePromotedbySamariumDiiodideZhiFangLI,PingLU,YongMinZHANGChinChemLett,,():LowvalentTitaniumInducedReductiveCyclizationofNitroCompoundsandAliphaticKetones:FacileSynthesisof,Dihdro(H),,Benzothiadiazine,DioxidesWeiHuiZhong,XiaoYuanChen,YongMinZhangChinJChem,,(),课题负责人:张良辅课题编号:课题负责人:刘汉范课题编号:课题负责人:王积涛课题编号:课题负责人:徐善生课题编号:,’双(四甲基环戊二烯基)二茂铁与五羰基铁和三乙腈三羰基钼的反应邓小斌~徐善生~王佰全,周秀中高等学校化学学报~,,课题负责人:周其林课题编号:课题负责人:曹卫国课题编号:AnEfficientandHighlyStereoselectiveSynthesisof,~,trans,Benzoyl,aryl,butyrolactonesCaoWeiguo,DingWeiyu,ChenYaliandQiuMengyaoSyntheticCommunications,,(),AnEfficientandHighlyStereoselectiveSynthesisofcisAcetylaryl,dimethyl,dioxospiro,,octadionesand,~,trans,Acetyl,aryl,butyrolactonesCaoWeiguo,DingWeiyu,ChenYaliandGaoJinsenSyntheticCommunications,,(),StudyontheReactionofcisAcetylaryl,dimethyl,dioxospiro,,octadioneswithMethanolCaoWeiguo,DingWeiyu,ChenYaliandGaoJinsenSyntheticCommunications,,(),,,三取代环丙烷衍生物与甲醇反应的研究曹卫国丁维钰童玮琦刘欣邱梦遥高等学校化学学报,,(),课题负责人:周锡庚课题编号:课题负责人:席振峰课题编号:EfficientSynthesisofCyclopentadienoneDerivativesbytheReactionofCarbonDioxidewith,Dilithio,dienesZhenfengXi*andQiulingSongJOrgChem,,课题负责人:江焕峰课题编号:课题负责人:庞震课题编号:Synthesis,CharacterizationandElectrochemicalPropertiesofSubstitutedHalfsandwichCobalt(I)ComplexesZhenPang*,XiufengHou,ZuenHuang,RuifangCaiandRuyiRuanSynthReactInorgMetOrgChem,,,TheCrystalStructureandReactivityof(,CHCOOCHCH)Co(CO)IZhenPang*,XiufengHou,RuifangCai,XigenZhouandZuenHuangSynthReactInorgMetOrgChem,,,SynthesisandStructureofEZ(,,tritertbutylphenylphosphinyl)N(tertbutyldimethylsilyl)N(pchrolophenyl)amino(,,tritertbutylphenyl)osphaethyleneph张立新,庞震*,周锡庚,蔡瑞芳,黄祖恩结构化学,,,课题负责人:张兆国课题编号
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