汉高化学(Henkel)工业清洗产品宣传册

S u st ai n ab ili ty R ep o rt 2 00 5 FMEE and FMES for Industrial Cleaning > Guide Formulations Chemical structure INCI name Fatty Methyl Ester Ethoxylates CAS numbers 65218-33-7 M . W 499.5 01 Product profile Fatty Methyl Ester Ethoxylates Cloud Point HLB Solution pH Fatty Acid Methyl Ester Active content approx. 15 approx. 6 approx.<2 Commercially available grades FMEE C18H36CO(OCH2CH2)7OCH3 Appearance Solid Content Yellow Liquid 70% Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 >100℃ Residue Chemical structure INCI name Fatty Methyl Ester Sulfonates CAS numbers 71338-19-24 M . W 676 02 Product profile Fatty Methyl Ester Sulfonates Cloud Point HLB Solution pH Fatty Acid Methyl Ester Active content approx. 12.5 approx. 7 approx.<2 Commercially available grades FMES C18H36CHSO3Na(OCH2CH2)7 Appearance Solid Content Yellow Liquid 70% Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 >100℃ Residue Cleaner for Automatic Bottle-Washing Plants The application of FMES in cleaners for automatic bottle-washing plants enables: > faster label removal > lower caustic solution concentration > longer life for the caustic solution > optimum clear gloss drying effect > absence of foaming and hence easy removal of labels from the cleaning liquor Formulation 15 % FMES 15 % Phosphoric acid, 75-85 % 10 % (Dow. Chemicals Div.) 10 % ®+ AM 8 % Isopropanol 42 % Water Application The formulation is normally used in a concentration of 0.5 %. Preparation The components are mixed in reverse order. Ed iti on : 1 1/ 20 06 Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 Asia Henkel Japan Ltd. Henkel Technology Center - Asia Pacific 27-7, Shin Isogo-cho, Isogo-ku, Yokohama 235-0017 Japan AEO-9 03 (Basf.Co）Pklssim Cleaner for Milking Equipment The best way to remove impurities and deposits of proteins, fat, carbohydrats, lactic acid, etc., is to use cleaners based on FMEE and FMES In this context it is important to note the considerably lower oral toxicity (LD50) of the Hordaphos products. For instance, the LD50 dosage in rats for Hordaphos CC MN is > 3,000 mg/kg body weight. In comparison, the value for phosphoric acid is in the region of 1530 mg/kg body weight. Formulation 20.0 % FMEE 10.0 % Phosphoric acid, 85 % 5.0 % 65.0 % Water Application The formulation can be both used for cold and warm appli- cations. A concentration of 0.5 % in water is recommended. Preparation The formulation components are mixed at room temperature in the given amount of water. Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 Asia Henkel Japan Ltd. Henkel Technology Center - Asia Pacific 27-7, Shin Isogo-cho, Isogo-ku, Yokohama 235-0017 Japan FMES Ed iti on : 1 1/ 20 06 04 Cleaner for Workshop and Garage Floors Workshop and garage floors are soiled chiefly with oil, grease, rust and dirt. The use of cleaners based on aliphatic or aromatic solvents is not possible in enclosed areas because of the fire hazard and toxicity of the gases. To achieve a satisfactory result in these conditions, aqueous formulations based on the FMEE products can be recommended. Formulation 30.0 % FMEE 5.0 % LAS (Stepan.Co.) 7.5 % Hostapur SAS 60 (Clariant, Functional Chemicals Div.) 57.5 % Water Application Depending on the degree of soiling, the concentrate diluted about 1:2 to 1:20 is applied to the surface to be cleaned and rinsed off with cold or warm water after about 15 minutes. Preparation The components are mixed together in the given order. Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 Asia Henkel Japan Ltd. Henkel Technology Center - Asia Pacific 27-7, Shin Isogo-cho, Isogo-ku, Yokohama 235-0017 Japan Ed iti on : 1 1/ 20 06 05 Cleaner for Workshop and Garage Floors Workshop and garage floors are contaminated primarily with oil, grease, rust and pigment dirt. The use of cleaners based on aliphatic or aromatic solvents is not possible in enclosed areas because of the fire hazard and toxicity of the gases. Nevertheless, aqueous formulations based on the FMEE product range can be recommended for achieving satisfactory cleaning results. If the floor is contaminated again by waste oil, the layer of oil does not penetrate into the surface for about 24 hours. The surface is made oil-repellent by the first cleaning operation. Formulation 23 % FMEE 7 % Sodium cumenesulfonate, 40 % solution 5 % 14 % Tetrapotassium pyrophosphate, 60 % 9 % Potassium hydroxide solution, 50 % 5 % Potassium silicate solution, 28 - 30° Bé 37 % Water Application When diluted up to 1:100 with water the formulation can be sprayed onto the contamination with suitable spraying equipment, left for a short time and then washed off with water. acid cleaner for workshops and garage floors is applied to the alkaline pretreated flooring, neutralization occurs. The dark discoloration of the flooring is removed. With this clea- ning cycle there is no risk of slipping. Preparation The formulation components are mixed together in reverse order at room temperature. Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 Asia Henkel Japan Ltd. Henkel Technology Center - Asia Pacific 27-7, Shin Isogo-cho, Isogo-ku, Yokohama 235-0017 Japan AEP (Dow.USA) Ed iti on : 1 1/ 20 06 06 Neutral Cleaner All-purpose cleaners are intended to be capable of removing a wide variety of dirt and soil even at a neutral pH. This formulation is noted for the fact that even in the technical sector, dirt such as cutting fluids and greases as well as mineral deposits can be removed completely. FMEE not only acts as an effective corrosion inhibitor but also ensures excellent cleaning results because of its dispersing and emulsifying properties (see picture). Formulation 5.00 % FMEE (Stepan USA.) 3.00 % Isopropanol 2.00 % Butyl diglycol 0.50 % Trisodium salt of nitrilotriacetic acid, 92 % 84.50 % Water Application The cleaner is used in a dilution of about 1:10 to 1:100 with water, depending on the degree of soiling. Should soiling be severe, the concentrated solution can be used. Preparation The components are mixed together at room temperature in reverse order. The formulation can be colored optionally with 0.0025 - 0.01 % of the green dye Sanolin Green R-3GL. Degreasing of a steel panel with the neutral cleaner formulation: left without and right with our product. Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 Asia Henkel Japan Ltd. Henkel Technology Center - Asia Pacific 27-7, Shin Isogo-cho, Isogo-ku, Yokohama 235-0017 Japan 10.00 % OP-10 (Shell.Co) 5.00 % FMES 5.00 % LAS Ed iti on : 1 1/ 20 06 07 (Arkema-inc.) Wax Remover Release agents, which are based on wax formulations, are used e.g. in the food industry, in plastic and aluminium industries. The instruments, which spread the wax as well as the mold surface itself have to be cleaned regularly from unmeant wax deposits. The best cleaning result can be achieved with an alkaline formulation which should be non-corrosive. Corrosiveness of the wax remover without and with our product. Steelpanel before and after cleaning with our wax remover (10 min dipping) Preparation The components are mixed together at room temperature in reverse order. Application The cleaner is used in concentrated form. The cleaning power can be enhanced by increasing the pH value with NaOH. Rinse with water after cleaning. 5 4 3 2 1 0 without w ei gh t l os s ca us ed b y co rr os io n [g /m 2 d] with Formulation 5.00 % FMEE (Shell.Co) 3.00 % Isopropanol 2.00 % Butyl diglycol 0.50 % Trisodium salt of nitrilotriacetic acid, 92 % 79.5 % Water Please note: This information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. USA Henkel Corporation 32100 Stephenson Highway Madison Heights, Michigan 48071 Tel: 866.332.7024 Fax: 248.583.2976 Canada Henkel Canada Corporation 2225 Meadowpine Blvd. Mississauga, Ontario, L5N 7P2 Canada Tel: 905.814.6511 Fax: 905.814.5391 Asia Henkel Japan Ltd. Henkel Technology Center - Asia Pacific 27-7, Shin Isogo-cho, Isogo-ku, Yokohama 235-0017 Japan 5.00 % OP-7 5.00 % OP-10 (Shell.Co) Ed iti on : 1 1/ 20 06 08 (Arkema-inc.) Credits We are customer driven. We develop superior brands and technologies. We aspire to excellence in quality. We strive for innovation. We embrace change. We are successful because of our people. We are committed to shareholder value. We are dedicated to sus- tainability and corporate social responsibility. We communicate openly and actively. We preserve the tradition of an open family company. Henkel is a leader with brands and technologies that make people’s lives easier, better and more beautiful. Vision and Values R & D and Sustainability Communications Phone: +49 (0)211-797-9336 Fax: +49 (0)211-798-5598 Email: wolfgang.zengerling henkel.com Sustainability Reporting & Stakeholder Dialogue Phone: +49 (0)211-797-3680 Fax: +49 (0)211-798-9393 Email: uwe.bergmann henkel.com Investor Relations Phone: +49 (0)211-797-3937 Fax: +49 (0)211-798-2863 Email: oliver.luckenbach henkel.com Corporate Citizenship Phone: +49 (0)211-797-6899 Fax: +49 (0)211-798-4040 Email: kai.von-bargen henkel.com Internet addresses www.henkel.com www.sd.henkel.com www.ir.henkel.com www.henkel-smile.com This document contains forward-looking statements which are based on the current estimates and assumptions made by the corporate management of Henkel KGaA. Forward-looking statements are char- acterized by the use of words such as expect, intend, plan, predict, assume, believe, estimate, anticipate and similar formulations. Such statements are not to be understood as in any way guaranteeing that those expectations will turn out to be accurate. Future performance and the results actually achieved by Henkel KGaA and its affiliated companies depend on a number of risks and uncertainties and may therefore differ materially from the forward-looking statements. Many of these factors are outside Henkel’s control and cannot be accura- tely estimated in advance, such as the future economic environment and the actions of competitors and others involved in the market- place. Henkel neither plans nor undertakes to update any forward- looking statements. Credits Further information Published by: Henkel KGaA, 40191 Düsseldorf, Germany © 2006 Henkel KGaA Editorial work and coordination: R & D and Sustainability Com- munications: Jan-Dirk Seiler-Hausmann, Wolfgang Zengerling; Corporate SHE and Product Safety: Dr. Michael Bahn, Uwe Bergmann, Dr. Norbert Fedtke, Christine Schneider, Marta Zak English translation, coordination and proofreading: ExperTeam® Neuss: Dave Brandt, Alice Milne, Susan Salms-Moss Design: Kuhn, Kammann & Kuhn AG, Cologne Typesetting: workstation gmbh, Bonn Photos: Christian Buck, Andreas Fechner, Steffen Hauser, Phillip Hympendahl, Wilfried Wolter, Henkel Printing: medialogik GmbH, Karlsruhe PR: 03 06 16.000, ISBN: 3-923324-02-2 The Sustainability Report is printed on Arctic Volume paper from Munkendahl. The paper is made from pulp bleached without chlorine. It consists of wood fibers originating from sustainably managed forests and certi- fied according to the rules of the Forest Stewardship Council (FSC). This publication was bound so as to be suitable for recycling, using Purmelt MicroEmission for the best possible occupational health and safety standards, and cover finished with waterborne Liofol laminating adhesives from Henkel. The printing inks contain no heavy metals. All product names are registered trademarks of Henkel KGaA, Düsseldorf, or its affiliated companies. Responsible Care® Sustainability performance Foreword 1 Henkel in brief 2 Management 4 Global challenges – Local responsibility 6 Dialogue 8 Product stewardship 10 Brands and Technologies 14 Laundry & Home Care 14 Cosmetics/Toiletries 16 Consumer and Craftsmen Adhesives 18 Henkel Technologies 20 Employees 22 Social commitment 26 Production sites worldwide 30 Regions 32 Indicators 37 Objectives 42 External ratings 44 Contact information/Credits Information on the Internet The symbol used at many points in this report indicates that more specific information can be found on the Internet. The references are listed on a link page provided on the Internet at www.sd.henkel.com. In addition, more detailed versions of the experts’ state- ments included in this report and the 2004 report can be found on the Internet. A GRI Index provides cross-references to the reporting elements and indicators of the Global Reporting Initiative (GRI) in this Sustainability Report and this year’s Annual Report and on the Internet. The Internet site also contains current news and background information about safety, health, environmental protection, and social responsibility at Henkel. In addition, all reports published since 1992 can be downloaded from the Internet site. ** Occupational accidents per 1,000,000 hours worked ** 2004 restated: The figures for 2004 have been restated owing to the retroactive application of IFRS 2 (Share-based Payment). In addition, actuarial gains and losses have also been set off in full against equity in accordance with IAS 19.93A, and this standard too has been applied retroactively effective January 1, 2004. 2004 comparable: Effective fiscal 2005, scheduled goodwill amortization ceases to be applicable. The figures for the years 2001 to 2004 have been adjusted accordingly to render them more readily comparable. Accounting changes implemented at Ecolab Inc., St. Paul, Minnesota, USA, have also been applied to the 2004 figures for better comparability. Further information about changes in the balance sheet accounting and valuation methods can be found in the notes on pages 69 and 70 of the 2005 Annual Report. Performance based on Henkel’s continued activities. Sustainability performance from 2001 to 2005 Business performance from 2001 to 2005 Environmental indicators per metric ton of output* Percent; index 2001 Heavy metals -69% Occupational accidents -63% Sulfur dioxide -47% Waste -35% Wastewater load -32% Energy -16% Carbon dioxide -13% Water 9% Volatile organic compounds 35% 2001 2002 2003 2004 2005 Profit (EBIT) +50% Sales +27% 130 120 110 100 ** Contents 09 CASE STUDY Logistics Henkel Turns to Aruba for Centralized Management, Security and Lower TCO With headquarters in Düsseldorf, Germany, and operations in more than 125 countries around the world, Henkel needed to deploy a wireless mobility solution on a global basis. The name behind such well-known brands as Persil, Loctite and Schwarzkopf, Henkel realised their existing wireless LAN (WLAN), based on legacy “thick” access points, would not scale, lacked the necessary security, and required too much administration. Henkel planned to deploy the next-generation WLAN to many of its locations around the world: It would support logistics within their warehouses, employee applications and guest access in their offices and training centres. Given the magnitude of the network, and its importance to