12 鲁玛斯DMTO烯烃回收和烯烃转化技术

Coal to Olefins 2010Coal to Olefins 2010 Lummus DMTO Recovery Technology/OCT --- Maximize the MTO Plant Profits Engineering Solutions . . . Delivering Results --- Maximize the MTO Plant Profits ???DMTO ??????????? ---??MTO????????? November, 2010. Beijing 2010?11? ?? AgendaAgenda •• Lummus Technology Company IntroductionLummus Technology Company Introduction Lummus Lummus ???????????? • Lummus Olefins Experience Lummus ??????? Engineering Solutions . . . Delivering Results Lummus ??????? • DMTO Recovery Technology Key Features DMTO??????????? • Olefins Conversion Technology ?????? 2 Lummus Technology Company OverviewLummus Technology Company Overview • Lummus was founded in 1907 Lummus?????1907? • Lummus Technology is a leading supplier of proprietary technologies to the petrochemical, refining and gas processing industries, licensing over 75 proprietary processes Engineering Solutions . . . Delivering Results processes ?????????????????????????? ???????????75????? • Lummus Technology is a Chicago Bridge & Iron (CB&I) company ??????????????? (CB&I) 3 CB&I Functional OrganizationCB&I Functional Organization Chicago Bridge & Iron Company N.V. Engineering Solutions . . . Delivering Results CB&I, Inc. Lummus Technology CB&I Lummus 4 CB&I Principal Worldwide OfficesCB&I Principal Worldwide Offices Geographic Regions ???????????????? North America ???????? Houston, USA London, UK Dubai, UAEBeaumont, USA Dallas, USA Brno, Czech Republic The Hague, NetherlandsHouston, USA Engineering Solutions . . . Delivering Results North America ???????? Central and South America ???????????????? Europe, Africa and Middle East ????????,???????????????????? Asia Pacific ???????????????? Total of approximately 17,000 employees ????????????????????17,000???????????? London, UK Perth, Australia Shanghai, China Tyler, USA The Woodlands, USAPlainfield, USA Wiesbaden, Germany Cairo, Egypt Singapore Bloomfield, USA Beijing, China 5 Lummus Petrochemical ProcessesLummus Petrochemical Processes PolystyreneStyreneEthylbenzeneNaphtha AGO/VGO Olefins Ethane LPG Ethylene C6-C8s C4s PolypropyleneOlefins Conversion (OCT) Dimerization Butene-2 Methanol to Olefins Methanol Engineering Solutions . . . Delivering Results Hexene-1 Methanol Butadiene Butylene Cumene Butadiene Extraction Maleic Anhydride Propane Dehydrogenation Butanes Propane Propylene Hydro- dealkylation Benzene Aromatics Saturation Propylene Phenol Dimethyl Carbonate Diphenyl Carbonate Comonomer Production (CPT) Butene-1 Butane Dehydrogenation CO O2 6 AgendaAgenda • Lummus Technology Company Introduction Lummus ?????? •• Lummus Olefins ExperienceLummus Olefins Experience Lummus Lummus ?????????????? Engineering Solutions . . . Delivering Results Lummus Lummus ?????????????? • DMTO Recovery Technology Key Features DMTO??????????? • Olefins Conversion Technology ?????? 7 Lummus Qualifications and ExperienceLummus Qualifications and Experience • Lummus is the premier light olefins licensor Lummus ?????????????? • Over 65 years of ethylene and propylene design experience from: ??65?????????????????????? – Steam cracking -???? Engineering Solutions . . . Delivering Results – Steam cracking -???? – Metathesis -?????????? – Propane dehydrogenation -???? – High olefin FCC -????????? – DMTO Recovery - DMTO???? 8 Lummus Qualifications and ExperienceLummus Qualifications and Experience • Over 180 operating units worldwide, accounting for 40% of world ethylene capacity and 30% of propylene capacity ??180????????????????????? 40%???30%????? • The DMTO recovery flowsheet is based upon Lummus’ proven and efficient ethylene technology Engineering Solutions . . . Delivering Results DMTO?????????Lummus?????????? ?? • Unparalleled level of experience is necessary to ensure a successful project ??????????????????? 9 Country Client Award Startup Status Capacity (Kta) Feed Brazil Rio Polimeros 2000 2005 Operating 535 C2/C3 China BP-Sinopec 2001 2005 Operating 950 Nap Poland PKN 2002 2005 Operating 300 Nap Taiwan Formosa 2003 2006 Operating 1200 Nap/GO China Maoming 2003 2006 Operating 640 Nap/LPG India IOCL 2004 2010 Operating 800 Nap China Fujian 2004 2009 Operating 800 Nap Egypt SIDPEC 2005 2011 Design 490 C2 New Ethylene Plant AwardsNew Ethylene Plant Awards Lummus Awards Since 2000 Engineering Solutions . . . Delivering Results Egypt SIDPEC 2005 2011 Design 490 C2 Singapore Shell 2005 2010 Operating 900 Nap Thailand CCC 2005 2010 Operating 800 Nap Saudi Arabia SCP 2005 2011 Design 1300 C2/C3/C5 China Tianjin 2006 2009 Operating 1000 Nap/HVGO Thailand PTTPE 2006 2009 Operating 1000 C2 China Zhenhai 2006 2010 Operating 1000 Nap/HVGO China Shenhua 2007 2010 Operating 300 Methanol Taiwan CPC 2007 2011 Design 720 Nap India Essar 2008 2013 Design 1300 Nap/C2/C3 India BCPL 2008 2012 Design 220 Nap/C2-C5 Philippines JG Summit 2009 2013 Design 320 Nap China Yanchang 2009 2012 Design 300 Methanol China Heyuan 2010 2013 Design 300 Methanol Lummus China Olefins ExperienceLummus China Olefins Experience • First ethylene plant design for Yanshan in early 1970s ???????????70????????? • Nearly 9 million metric tons of Chinese ethylene capacity produced in plants utilizing Lummus ethylene technology China Ethylene Experience ???????????????????????????????? Engineering Solutions . . . Delivering Results ?????900??/????????Lummus??? – 7.2 million metric tons in 16 new plants 16???????720??/??? – 1.6 million metric tons in 12 plant expansion 160??/???????12?????? – 28 ethylene projects in China producing 70% of China’s ethylene capacity ??????28??????????????70% 11 Lummus DMTO ExperienceLummus DMTO Experience • Lummus and SYN have signed a cooperation agreement to jointly offer the DMTO reaction and DMTO recovery technology worldwide Lummus???????????????????DMTO????? ???? • Brings together about 30 years of DMTO and more than 65 years of SYN/Lummus Cooperation ????????????????/Lummus ???????????? Engineering Solutions . . . Delivering Results • Brings together about 30 years of DMTO and more than 65 years of olefins recovery experience ??30??DMTO ?????????65??????????? • This cooperation leads to ??????????? – Proven close relationship to provide design that is fully optimized with no design interface issues ????????????????????????????? – Faster on-stream and stable commercial production ????????????????????? 12 Lummus DMTO ExperienceLummus DMTO Experience • SYN and Lummus have the only commercial MTO unit in operation since Aug. 2010: Shenhua Baotou (600 KTA) ?????Lummus??????????MTO?????????? ??2010?8??????DMTO???60??/?? • Operating experience from Shenhua Baotou will be applied to all future designs, commissioning and start-up Only Commercial Operating MTO unit ????????????????????????????????????????????MTO???????? Engineering Solutions . . . Delivering Results ??????????????????????????????? • Lummus has largest market share, has been selected by 4 MTO projects with 2000 KTA total capacity Lummus ??????????????????????4????? ?????DMTO??????200??/????? • The technology was selected after careful review and comparison by each client?and based on high recovery?low energy consumption and low investment ??????????????????????????????? ??????? 13 AgendaAgenda • Lummus Technology Company Introduction Lummus ?????? • Lummus Olefins Experience Lummus ??????? Engineering Solutions . . . Delivering Results Lummus ??????? •• DMTO Recovery Technology Key FeaturesDMTO Recovery Technology Key Features DMTODMTO?????????????????????? • Olefins Conversion Technology ?????? 14 DMTO Recovery Process OverviewDMTO Recovery Process Overview Compression & Water Wash ???????????????????? Depropanizer ???????????????? Compression ???????? Caustic Wash ???????? Drying ???????? Depentanizer ???????????????? Compression ???????? Feed from Reactor C6+ C4 & C5 to OCU Engineering Solutions . . . Delivering Results Demethanizer ???????????????? ???????? Propylene Fractionator ???????????????????? Deethanizer ???????????????? Acetylene Converter ???????????????????? Ethylene Fractionator ???????????????????? Propane ???????? Propylene Product ???????????????? Ethylene Product ???????????????? Reactor ???????????????????????????? Ethane???????? Fuel Gas ???????????? Hydrogen ???? 15 Highlights of Lummus TechnologyHighlights of Lummus Technology • Lummus DMTO recovery flowsheet engineered for: Lummus DMTO ???????????: – Low energy consumption ??? – Low investment cost ??? Superior Plant Performance ???????????????????????????? Engineering Solutions . . . Delivering Results – Low investment cost ??? – High products recovery ???? • Very low energy consumption resulting from very efficient process design and heat integration between DMTO reactor and recovery sections ???????????????????????????? ???????. 16 Highlights of Lummus TechnologyHighlights of Lummus Technology • Very low investment cost resulting from: ?????????????: – Single refrigeration system with coldest temperature of only -40°C ??????-40°C??????? Superior Plant Performance ???????????????????????????? Engineering Solutions . . . Delivering Results ??????-40°C??????? – All carbon steel equipment ???????? – Simplified process with fewest pieces of equipment ??????????????? • Lummus ethylene plant track record of high on-stream factor brings higher operating hours, also could reduce investment cost ?????Lummus??????????????????? ???????, ?????????? 17 Highlights of Lummus TechnologyHighlights of Lummus Technology • The Lummus design is inherently safe Lummus MTO??????????????? • Lack of demonstrated experience and know-how in dealing with NOx could lead to potentially catastrophic safety failure in the MTO plant ??????NOx??????????,???MTO??????? Inherent Safety ???????????????????????? Engineering Solutions . . . Delivering Results NOx , MTO ????? • Lummus has the most comprehensive understanding of NOx build- up and safety in the industry Lummus???NOx?????????????? • The DMTO recovery technology utilizes this understanding and know-how, ensuring the process configuration and full process design will offer the highest level of plant safety ????????????????,??Lummus DMTO????? ???????????????? 18 Highlights of Lummus TechnologyHighlights of Lummus Technology • The MTO reactor effluent has components that can lead to extensive fouling and equipment corrosion?if not properly controlled would lead to high maintenance costs and lower plant operating hours MTO???????????????????????,????? ??????,????????????,???????????? Fouling and Corrosion Control ???????????????????????????????? Engineering Solutions . . . Delivering Results ??????,????????????,???????????? • Lummus’ proprietary know-how and equipment design limit fouling and corrosion. Lummus????????????????????? – Additives injection ??????? – Design conditions ??????? – Use of HELIXCHANGER® ?????????? HELIXCHANGER® 19 AgendaAgenda • Lummus Technology Company Introduction Lummus ?????? • Lummus Olefins Experience Lummus ??????? Engineering Solutions . . . Delivering Results Lummus ??????? • DMTO Recovery Technology Key Features DMTO??????????? •• Olefins Conversion TechnologyOlefins Conversion Technology ???????????? 20 Lummus OCTLummus OCT • The C4 & C5 Olefins from MTO units are good feed to an Olefins Conversion Unit (OCU) to increase propylene product MTO?????C4/C5 ???????????????????? – Operating margins are improved since C4’s & C5’s are upgraded from fuel value to propylene value ??????C4/C5?????????, ????????? • Lummus offers the only commercially demonstrated Olefins Engineering Solutions . . . Delivering Results • Lummus offers the only commercially demonstrated Olefins Conversion Technology ???????Lummus?????????????? – 29 plants licensed since 2002 including 5 units in China, nearly 7 million tons of propylene capacity, about 10% of world propylene capacity ?2002????????29????????????5?, ????? ???700??/?,?????????10% – DMTO – OCU integration under design for one of the MTO projects ?????MTO??????DMTO-OCU?????????? Lummus???????? ???????? ???????? ???????? ???????? ???????? ???????? ???????????????? ???????????????? ???????? C4???????? ?? Lyondell 1983 1985 45 ??? ????? MTBE ??? ?? BASF/Fina 2000 2004 30 ??? ??? C4 ?? ?? 2002 2004 14.5 ??? ??? C4 ?? ???? 2002 2005 16 ??? ??? C4 ?? ???? 2003 2006 25 ??? ?? C4 & FCC?? ?? ?? 2003 2006 14 ??? ?????? C4 Engineering Solutions . . . Delivering Results ?? ?? 2003 2006 14 ??? ?????? C4 ?? KPIC 2004 2005 11 ??? ?????? C4 ??? PCS 2004 2006 20 ??? ??? C4 ?? Hellenic 2004 2008 10 ??? ?????? C4 ??? Carmel 2004 2006 18 ??? ?????? C4 ?? LG 2005 2006 12.2 ??? ??? C4 ???? Titan 2005 2007 11.5 ??? ??? C4 Lummus???????? ???????? ???????? ???????? ???????? ???????? ???????? ???????????????? ???????????????? ???????? C4???????? ?? ?????? 2005 2009 36.2 ??? ??? C4 ?? OMV 2005 2008 23.8 ??? ??? C4 ????? ??? Borouge 2005 2010 75.2 ??? ???????? C4 ????? Saudi/Chevro n Phillips 2005 2010 20 ??? ??? C4 ?? CCC 2005 2009 26.1 ??? ??? C4 Engineering Solutions . . . Delivering Results ?? CCC 2005 2009 26.1 ??? ??? C4 ????? Ibn Zahr 2006 2009 25 ??? ??? C4 ? MTBE??? ?? ?? 2006 2008 16.6 ??? ??? C4 ????? PT Pertamina 2006 2010 17.9 ??? ??C4 ? FCC ?? ?? ?? 2006 2008 15 ??? ??? C4 ?? ?? 2006 2009 20.6 ??? ??? C4 ?? PTT Chem 2007 2009 68 ??? ??? C4 ?? ???? 2007 2011 63 ??? ??? C4 ??? ????? 2007 2011 43 ?? ??? C4 Lummus???????? ???????? ???????? ???????? ???????? ???????? ???????? ???????????????? ???????????????? ???????? C4???????? ?? ???? 2008 2011 16.5 ??? ??????C4 ?? IRPC 2008 2011 10 ??? ???C4 ???? Takreer 2008 2011 35 ??? ?????? C4 ????? ??/??? ? 2009 2012 28 ??? ?? C4 ?? ???? 2010 2013 9 ??? DMTO C4 Engineering Solutions . . . Delivering Results ?? ?? 2010 2013 15 ??? ?? C4 ?? ?? 2010 2011 11.5 ??? ?????? C4 DMTO plus OCUDMTO plus OCU Light Olefin Recovery Section ???????????????? Fuel Gas ???????????? Ethylene Product ???????????????? Propylene Product ????????????????C4’s & C5’s MTO Reactor Effluent MTO???????????? Quench Section ???????????????? 12% increase in C2/C3 Product ????????12% ????????????+???????????????? Engineering Solutions . . . Delivering Results ???????????????? ???????? ????????????????C4’s & C5’s C6+ MTO???????????? Water ???? OCU ???????????????? C4’s & C5’s ???????????????????? Vents ???????????? Heavy Purge ???????????? Metathesis reactionMetathesis reaction Engineering Solutions . . . Delivering Results Butene+Ethylene ???????? + ???????? react to form ???????????????? OCT upgrades low-cost butylenes & pentenes to high-price propylene ???????????????????????????????????????????????????????????????????????????????????????????????????? 2 Propylene 2 ???????? Adds $50MM per year to the operating margin for a 600 kTA MTO unit ????????????????60????????/????????MTO????????????????????????????????5000???????????????????????????????? Pentenes undergo similar reactions ???????????????????????????????????????? Ethylene Feed Propylene Product Lights Purge Recycle Ethylene OCT Reactor Ethylene Column Propylene Column Guard Bed Ultra-High Purity Propylene >99.9+% ????????????????????99.9+% Simple & Low Cost Flow Scheme Engineering Solutions . . . Delivering Results C4 & C5 Feed C4 Plus C4 Recycle No Superfractionators Required ???????????????????????????????? Reaction is Exothermic – No Energy is Consumed to produce propylene ????????????????---???????????????????????????????????????????? Fixed Bed Reactor ???????????????? ???????? OCT end-user advantages • OCT is a highly efficient process to utilize C4&C5 olefins OCT?????C4/C5??????? • Less than 2% of side products are produced ?????2%???? • Lowest investment for on-purpose Engineering Solutions . . . Delivering Results • Lowest investment for on-purpose propylene production ??????????????????? • UHP grade propylene � 99.9+% ????????????99.9% • PP unit operating cost advantage ????????????? • No energy consumption in reaction ???????? • Commercially well proven ????????? Lummus process design is safe, simplified and reliable due to our extensive olefins recovery experience Lummus is the leading supplier of olefins technology in China and worldwide The SYN-Lummus cooperation ensures a fully optimized design without interfaces issue ConclusionsConclusions Lummus experience and design efficiency will help maximize the MTO plant profits Engineering Solutions . . . Delivering Results Coldest temperature of -40�C allowing for no NOx safety concerns and a single refrigeration system and all carbon steel equipment Lummus MTO recovery technology is being selected for 4 projects. Shenhua Baotou MTO unit started operation in Aug 2010 Experience with trace impurity removal and the limitation of fouling and corrosion throughout the unit will ensure long cycle times and minimum maintenance costs Experience gained from Shenhua Baotou will be directly applied. This experience will ensure the quick startup and high reliability for the project Integration with an Olefins Conversion Unit increases Ethylene + Propylene production by 12% C4’s & C5’s are effectively utilized MTO plant profits 29 Lummus???????????????????????? ???????????????????????????????????????? ???????????????????????????????????????? ???????????????????????????????? Lummus ???????????????? ???????????????????????????????????? ???????????????????????? Lummus DMTO ????????????????????Lummus???????? ???????????????????????????????????????????? ???????????????????? ConclusionsConclusions Lummus ???????????????????????????????????????? ????????MTO???????????????????????????????????? Engineering Solutions . . . Delivering Results ????????????????????????????-40 �C ???????????????????????????????????????? ???????????????????????????????????????? ???????????????????????????????????????? ???????????????????????????????????????? ???????????????????????????? Lummus DMTO ????????????????????????4???????? ????????????, ???????????????? MTO???????????????????? 2010????8???????????????????? Lummus???????????????????????????? ???????????????????????????????????????????? ???????????????????????????????????????????? ???????????????????????????????????? ???????????????????????????????????? ???????????????????????????????????? ???????????????????????????????? ????????????????????DMTO???? ???????????????????????????????????? C4????C5 ???????????????????? ???????????????????????????????? 12%???????? Contact Information ???????????????? Mr. Wang Hao ???? ???? Director of Business Development Engineering Solutions . . . Delivering Results31 Director of Business Development Lummus Technology Inc. – China Lummus ????????????????-???????????????????????????????? Fax: +86 10 59756292 Tel(o): +86 10 59209628 Cell: +86 13910686742 Email: fhwang@cbi.com