3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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Material Safety Data Sheet
Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: FC-4430 FLUORAD (TM) Fluorosurfactant
MANUFACTURER: 3M
DIVISION: Performance Materials Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/07/2003
Supercedes Date: 01/13/2003
Document Group: 09-6918-8
Product Use:
Specific Use: FLOW CONTROL AGENT
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
FLUOROALIPHATIC POLYMERIC ESTERS +(6391P) Trade Secret 85 - 95
POLYETHER POLYMER +(6417P) Trade Secret 5 - 10
1-METHYL-2-PYRROLIDINONE 872-50-4 1 - 2
TOLUENE 108-88-3 < 1
2-PROPENOIC ACID, 2-
[METHYL[(NONAFLUOROBUTYL)SULFONYL]AMINO]ETHYL ESTER
67584-55-8 0 - 0.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: liquid
Odor, Color, Grade: viscous, amber color with distinctive odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction. (CAS No. 67584-55-8) May
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Toluene (CAS
No. 108-88-3) and 1-Methyl-2-pyrrolidinone (872-50-4)
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing.
Skin Contact:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
May be absorbed through skin and cause target organ effects.
(CAS No. 67584-55-8)
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Single exposure, above recommended guidelines, may cause:
Pulmonary Edema: Signs/symptoms may include chest discomfort, shortness of breath, significant cough with frothy sputum
production, bluish colored skin (cyanosis), increased heart rate and possible respiratory failure, and may be fatal.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
Target Organ Effects:
Blood Effects: Signs/symptoms may include generalized weakness and fatigue, skin pallor, and fever.
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure, above recommended guidelines, may cause:
Bone Marrow Effects: Signs/symptoms may include generalized weakness, pallor of the skin, fatty infiltration of the bone
marrow, decreases in the numbers of circulating blood cells, increased susceptibility to infection.
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Toluene (CAS No. 108-88-3) and 1-Methyl-2-pyrrolidinone (872-50-4)
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
Testing indicates this product is harmful to aquatic organisms (10 mg/L < Lowest LC50, EC50, or IC50 < or = 100 mg/L). Testing
indicates this product has minimal toxicity to wastewater treatment organisms (100 mg/L < sludge respiration IC50 < or = 1000
mg/L).
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available
Flash Point >=100 ºC [Test Method: Closed Cup]
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIA
Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure
demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for
exposed areas of the head.
Unusual Fire and Explosion Hazards: Not applicable. Non-flammable: ordinary combustible material.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical
ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Working from around the edges
of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient
absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Collect the resulting
residue containing solution. Place in a closed container approved for transportation by appropriate authorities.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid contact with oxidizing agents. Do not breathe vapors. Avoid skin contact. Do not eat, drink or smoke when using this product.
Wash exposed areas thoroughly with soap and water. Avoid eye contact with vapors, mists, or spray. Use general dilution ventilation
and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits. If ventilation is not adequate,
use respiratory protection equipment.
7.2 STORAGE
Store away from oxidizing agents. Keep container in well-ventilated area.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust ventilation on open containers. For those situations where the fluid might be exposed to extreme
overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal
decomposition products below their exposure guidelines.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. Avoid eye contact.
The following eye protection(s) are recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber, Polyethylene/Ethylene Vinyl Alcohol.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Fullface supplied-air respirator. Consult the current 3M Respiratory Selection Guide for additional information or
call 1-800-243-4630 for 3M technical assistance.
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1-METHYL-2-PYRROLIDINONE AIHA TWA 10 ppm Skin Notation*
TOLUENE ACGIH TWA 50 ppm Skin Notation*; Table A4
TOLUENE CMRG STEL 75 ppm Skin Notation*
TOLUENE OSHA TWA,
Vacated
100 ppm
TOLUENE OSHA STEL,
Vacated
150 ppm
TOLUENE OSHA TWA 200 ppm Table Z-2
TOLUENE OSHA CEIL 300 ppm Table Z-2
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous
membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter
skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: liquid
Odor, Color, Grade: viscous, amber color with distinctive odor
General Physical Form: Liquid
Autoignition temperature No Data Available
Flash Point >=100 ºC [Test Method: Closed Cup]
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
Boiling point 200 ºC
Vapor Density 5.7 [Ref Std: AIR=1]
Vapor Pressure 0.29 mmHg [Details: CONDITIONS: @ 20C]
Specific Gravity 1.15 [Ref Std: WATER=1] [Details: CONDITIONS: @ 25C]
pH Not Applicable
Melting point Not Applicable
Solubility in Water Complete [Details: @ 25 C]
Evaporation rate No Data Available
Volatile Organic Compounds 29 g/l [Test Method: calculated SCAQMD rule 443.1]
Percent volatile <=1 %
VOC Less H2O & Exempt Solvents 29 g/l [Test Method: calculated SCAQMD rule 443.1]
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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Viscosity 3000 - 15000 centipoise
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Fluoride During Combustion
Oxides of Nitrogen During Combustion
Oxides of Sulfur During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Test Organism Test Type Result
Water flea, Daphnia magna 48 hours Effect Concentration 50% 99 mg/l
Green algae, Selenastrum capricornutum 96 hours Effect Concentration 50% 763 mg/l
Fathead Minnow, Pimephales promelas 96 hours Lethal Concentration 50% 765 mg/l
Activated Sludge, Effect Concentration 50% 786.2 mg/l
CHEMICAL FATE INFORMATION
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion
products will include HF. Facility must be capable of handling halogenated materials.
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
98-0212-2943-4, 98-0212-2944-2, 98-0212-2945-9, 98-0212-2946-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
This material contains one or more substances which are subject to a TSCA Consent Order or Significant New Use Rule.
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
1-METHYL-2-PYRROLIDINONE 872-50-4 1 - 2
TOLUENE 108-88-3 < 1
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
FLUOROALIPHATIC POLYMERIC ESTERS
+(6391P)
Trade Secret Toxic Substances Control Act (TSCA) 5
SNUR or Consent Order Chemicals
Applicable
1-METHYL-2-PYRROLIDINONE 872-50-4 Toxic Substances Control Act (TSCA) 4 Test
Rule Chemicals
Applicable
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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Ingredient C.A.S. No. Classification
1-METHYL-2-PYRROLIDINONE 872-50-4 *Developmental Toxin
TOLUENE 108-88-3 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
Additional Information: New Jersey Trade Secret Registry (EIN) 04499600-+
INTERNATIONAL REGULATIONS
Contact 3M for more information.
WHMIS: Hazardous
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).
Revision Changes:
3M MATERIAL SAFETY DATA SHEET FC-4430 FLUORAD (TM) Fluorosurfactant 05/07/2003
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Section 1: Division name was modified.
Section 3: Other potential health effects comment was added.
Section 3: Immediate skin hazard(s) comment was added.
Section 3: Potential effects from skin contact comment was added.
Section 3: Immediate other hazard(s) comment was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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